12). What is the major product of the following reaction?ОНС.HO-H₂CОНС.(A)NO₂(D)SnCl2, then H3O+.NO2 HOOC(B)?NH₂HỌỌC,00(E)NO₂ HO-H₂C.NH₂(C)NH₂

3-nitro benzaldehyde on reduction with SnCl2 (Then H3O^+) gives 3-amino benzaldehyde.

Answered: 12). What is the major product of the…

12). What is the major product of the following reaction? ОНС. HO-H₂C ОНС. (A) NO₂ SnCl2, then H3O+ .NO2 HOOC, NH₂ HOOC (B) ? NO₂ HO-H₂C. NH₂ (C) NH₂

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter14: Conjugated Compounds And Ultraviolet Spectroscopy

Section14.SE: Something Extra

Problem 27AP

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Concept explainers

Reactions at the Alpha Carbon Atom

The position next to the ketone or aldehyde functional group is termed as alpha position and the reaction which occurs at alpha position is called alpha substitution reaction. In an alpha substitution reaction, the alpha proton atom is substituted by an electrophile by the formation of an enol intermediate or enolate ion intermediate. Most of the carbonyl compounds go through an alpha substitution reaction.

Question

12). What is the major product of the following reaction?
ОНС.
HO-H₂C
ОНС.
(A)
NO₂
(D)
SnCl2, then H3O+
.NO2 HOOC
(B)
?
NH₂
HỌỌC,
00
(E)
NO₂ HO-H₂C.
NH₂
(C)
NH₂

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