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16.18 For the gas-phase reaction 2NO₂ + F₂ → 2NO₂F, the rate constant k is 38 dm³ mol-¹ s¹ at 27°C. The reaction is first- order in NO₂ and first-order in F₂. (a) Calculate the number of moles of NO₂, F2, and NO₂F present after 10.0 s if 2.00 mol of NO₂ is mixed with 3.00 mol of F₂ in a 400-dm³ vessel at 27°C. (b) For the system of (a), calculate the initial reaction rate and the rate after 10.0 s.

16.18 For the gas-phase reaction 2NO₂ + F₂ → 2NO₂F, the rate constant k is 38 dm³ mol-¹ s¹ at 27°C. The reaction is first- order in NO₂ and first-order in F₂. (a) Calculate the number of moles of NO₂, F2, and NO₂F present after 10.0 s if 2.00 mol of NO₂ is mixed with 3.00 mol of F₂ in a 400-dm³ vessel at 27°C. (b) For the system of (a), calculate the initial reaction rate and the rate after 10.0 s.

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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16.18 For the gas-phase reaction 2NO₂ + F₂ → 2NO₂F, the rate constant k is 38 dm³ mol-¹ s¹ at 27°C. The reaction is first- order in NO₂ and first-order in F₂. (a) Calculate the number of moles of NO₂, F2, and NO₂F present after 10.0 s if 2.00 mol of NO₂ is mixed with 3.00 mol of F₂ in a 400-dm³ vessel at 27°C. (b) For the system of (a), calculate the initial reaction rate and the rate after 10.0 s.
Transcribed Image Text:16.18 For the gas-phase reaction 2NO₂ + F₂ → 2NO₂F, the rate constant k is 38 dm³ mol-¹ s¹ at 27°C. The reaction is first- order in NO₂ and first-order in F₂. (a) Calculate the number of moles of NO₂, F2, and NO₂F present after 10.0 s if 2.00 mol of NO₂ is mixed with 3.00 mol of F₂ in a 400-dm³ vessel at 27°C. (b) For the system of (a), calculate the initial reaction rate and the rate after 10.0 s.
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