16.54 Using data from Table 16.2, calculate the molar sol- ubility of CaF2. ABLE 16.2 Solubility Products of Some Slightly Soluble lonic Compounds at 25°C Ksp Compound Aluminum hydroxide [Al(OH)3] Barium carbonate (BaCO3) Barium fluoride (BaF₂) Barium sulfate (BaSO4) Bismuth sulfide (Bi₂S3) Cadmium sulfide (CdS) Calcium carbonate (CaCO3) Calcium fluoride (CaF₂) Calcium hydroxide [Ca(OH)₂] Calcium phosphate [Ca3(PO4)₂] Chromium(III) hydroxide [Cr(OH)3] Cobalt(II) sulfide (COS) Copper(I) bromide (CuBr) Copper(I) iodide (Cul) Copper(II) hydroxide [Cu(OH)₂] Copper(II) sulfide (CuS) Iron(II) hydroxide [Fe(OH)₂] Iron(III) hydroxide [Fe(OH)3] Iron(II) sulfide (FeS) Lead(II) carbonate (PbCO3) Lead(II) chloride (PbCl₂) 1.8 × 10-33 8.1 × 10-⁹ 1.7 x 10-6 1.1 X 10-10 1.6 × 10-72 8.0 × 10-28 8.7 × 10-⁹ 4.0 × 10-¹1 8.0 x 10-6 1.2 × 10-26 3.0 × 10-29 4.0 × 10-21 4.2 × 10-8 5.1 × 10-12 2.2 × 10-20 6.0 × 10-37 1.6 × 10-14 1.1 X 10-36 6.0 × 10-19 3.3 × 10-14 2.4 x 10-4 Compound Lead(II) chromate (PbCrO4) Lead(II) fluoride (PbF₂) Lead(II) iodide (Pbl₂) Lead(II) sulfide (PbS) Magnesium carbonate (MgCO3) Magnesium hydroxide [Mg(OH)₂] Manganese(II) sulfide (MnS) Mercury(I) chloride (Hg₂Cl₂) Mercury(II) sulfide (HgS) Nickel(II) sulfide (NiS) Silver bromide (AgBr) Silver carbonate (Ag₂CO3) Silver chloride (AgCl) Silver iodide (Agl) Silver sulfate (Ag2SO4) Silver sulfide (Ag₂S) Strontium carbonate (SrCO3) Strontium sulfate (SrSO4) Tin(II) sulfide (SnS) Zinc hydroxide [Zn(OH)₂] Zinc sulfide (ZnS) Ksp 2.0 × 10-14 4.1 × 10-8 1.4 × 10-8 3.4 x 10-28 4.0 × 10-5 1.2 × 10-¹¹ 3.0 × 10-14 18 3.5 × 10 4.0 × 10-54 1.4 x 10-24 7.7 × 10-13 8.1 X 10 1.6 × 10-10 -12 -17 8.3 × 10 1.4 x 10-5 6.0 x 10-51 1.6 × 10-⁹ 3.8 × 10-7 1.0 × 10-26 1.8 × 10-14 3.0 × 10-23

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Chapter14: Equilibria In Acid-base Solutions
Section: Chapter Questions
Problem 37QAP: Given three acid-base indicators—methyl orange (end point at pH 4), bromthymol blue (end point at...
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16.54 Using data from Table 16.2, calculate the molar sol-
ubility of CaF2.
TABLE 16.2 Solubility Products of Some Slightly Soluble lonic Compounds at 25°C
Ksp
1.8 × 10-33
8.1 × 10-⁹
1.7 x 10-6
1.1 X 10-10
1.6 × 10-72
8.0 × 10-28
8.7 × 10-⁹
Compound
Aluminum hydroxide [Al(OH)3]
Barium carbonate (BaCO3)
Barium fluoride (BaF₂)
Barium sulfate (BaSO4)
Bismuth sulfide (Bi₂S3)
Cadmium sulfide (CdS)
Calcium carbonate (CaCO3)
Calcium fluoride (CaF₂)
Calcium hydroxide [Ca(OH)₂]
Calcium phosphate [Ca3(PO4)₂]
Chromium(III) hydroxide [Cr(OH)3]
Cobalt(II) sulfide (COS)
Copper(I) bromide (CuBr)
Copper(I) iodide (Cul)
Copper(II) hydroxide [Cu(OH)₂]
Copper(II) sulfide (CuS)
Iron(II) hydroxide [Fe(OH)₂]
Iron(III) hydroxide [Fe(OH)3]
Iron(II) sulfide (FeS)
Lead(II) carbonate (PbCO3)
Lead(II) chloride (PbCl₂)
4.0 × 10-11
8.0 × 10-6
1.2 × 10-26
3.0 × 10-29
4.0 × 10-21
4.2 × 10-8
5.1 × 10-¹2
2.2 × 10-20
6.0 × 10-37
1.6 × 10-14
1.1 ×
10-36
6.0 ×
10-19
3.3 ×
10-14
2.4 x
10-4
Compound
Lead(II) chromate (PbCrO4)
Lead(II) fluoride (PbF₂)
Lead(II) iodide (Pbl₂)
Lead(II) sulfide (PbS)
Magnesium carbonate (MgCO3)
Magnesium hydroxide [Mg(OH)₂]
Manganese(II) sulfide (MnS)
Mercury(I) chloride (Hg₂Cl₂)
Mercury(II) sulfide (HgS)
Nickel(II) sulfide (NiS)
Silver bromide (AgBr)
Silver carbonate (Ag₂CO3)
Silver chloride (AgCl)
Silver iodide (AgI)
Silver sulfate (Ag2SO4)
Silver sulfide (Ag₂S)
Strontium carbonate (SrCO3)
Strontium sulfate (SrSO4)
Tin(II) sulfide (SnS)
Zinc hydroxide [Zn(OH)₂]
Zinc sulfide (ZnS)
Ksp
2.0 × 10-14
4.1 × 10-8
1.4 × 10-8
3.4 × 10-28
4.0 × 10-5
1.2 × 10-¹1
3.0 × 10-14
3.5 × 10-18
4.0 × 10-54
1.4 x 10-24
7.7 × 10-13
8.1 x 107
-12
1.6 × 10-10
8.3 × 10-¹7
1.4 x 10-5
6.0 × 10-51
1.6 × 10-⁹
3.8 x 10-7
1.0 × 10-26
1.8 × 10-14
3.0 × 10-23
Transcribed Image Text:16.54 Using data from Table 16.2, calculate the molar sol- ubility of CaF2. TABLE 16.2 Solubility Products of Some Slightly Soluble lonic Compounds at 25°C Ksp 1.8 × 10-33 8.1 × 10-⁹ 1.7 x 10-6 1.1 X 10-10 1.6 × 10-72 8.0 × 10-28 8.7 × 10-⁹ Compound Aluminum hydroxide [Al(OH)3] Barium carbonate (BaCO3) Barium fluoride (BaF₂) Barium sulfate (BaSO4) Bismuth sulfide (Bi₂S3) Cadmium sulfide (CdS) Calcium carbonate (CaCO3) Calcium fluoride (CaF₂) Calcium hydroxide [Ca(OH)₂] Calcium phosphate [Ca3(PO4)₂] Chromium(III) hydroxide [Cr(OH)3] Cobalt(II) sulfide (COS) Copper(I) bromide (CuBr) Copper(I) iodide (Cul) Copper(II) hydroxide [Cu(OH)₂] Copper(II) sulfide (CuS) Iron(II) hydroxide [Fe(OH)₂] Iron(III) hydroxide [Fe(OH)3] Iron(II) sulfide (FeS) Lead(II) carbonate (PbCO3) Lead(II) chloride (PbCl₂) 4.0 × 10-11 8.0 × 10-6 1.2 × 10-26 3.0 × 10-29 4.0 × 10-21 4.2 × 10-8 5.1 × 10-¹2 2.2 × 10-20 6.0 × 10-37 1.6 × 10-14 1.1 × 10-36 6.0 × 10-19 3.3 × 10-14 2.4 x 10-4 Compound Lead(II) chromate (PbCrO4) Lead(II) fluoride (PbF₂) Lead(II) iodide (Pbl₂) Lead(II) sulfide (PbS) Magnesium carbonate (MgCO3) Magnesium hydroxide [Mg(OH)₂] Manganese(II) sulfide (MnS) Mercury(I) chloride (Hg₂Cl₂) Mercury(II) sulfide (HgS) Nickel(II) sulfide (NiS) Silver bromide (AgBr) Silver carbonate (Ag₂CO3) Silver chloride (AgCl) Silver iodide (AgI) Silver sulfate (Ag2SO4) Silver sulfide (Ag₂S) Strontium carbonate (SrCO3) Strontium sulfate (SrSO4) Tin(II) sulfide (SnS) Zinc hydroxide [Zn(OH)₂] Zinc sulfide (ZnS) Ksp 2.0 × 10-14 4.1 × 10-8 1.4 × 10-8 3.4 × 10-28 4.0 × 10-5 1.2 × 10-¹1 3.0 × 10-14 3.5 × 10-18 4.0 × 10-54 1.4 x 10-24 7.7 × 10-13 8.1 x 107 -12 1.6 × 10-10 8.3 × 10-¹7 1.4 x 10-5 6.0 × 10-51 1.6 × 10-⁹ 3.8 x 10-7 1.0 × 10-26 1.8 × 10-14 3.0 × 10-23
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