kindly sopve step by step 10:20 AM O1d1/12-Bromo pentane on reaction with NaOH, produces twostructural alkene P(81%) and Q(19%). If more stable formof P is 'R' alkene. Then for the following sequence, which ofthe following statements is CORRECT :(1) Br, /H,0(ii)HBr ČCI,1)NaOH/1,(i)B-H -THF(iii) PCC, CH,Cla· (Y) – ) Buli(iii) CH,I1) (CH SH), HCi(R)→ (X)→(Z)(ii) Nal acetoneiv) dil. H SO,(iv)H Raney NiO Total stable conformation possible for Z is 3.X will give red color with cerric ammonium nitrate.Y will give white non crystalline product with aq.NAHSO3

Answered: Image /qna-images/answer/e09ac351-59bf-43ae-9d47-7b8cf7230b92.jpg

2-Bromo pentane on reaction with NaOH, produces two structural alkene P(81%) and Q(19%). If more stable form of P is 'R' alkene. Then for the following sequence, which of the following statements is CORRECT : 6) Br, H,0 (H)HBu ĆCI, 1)NaOH/I, (1)B-H, -THF Gi1) PCC,CH;CI, (1) Buli (ii) CH,I iv)H,/Raney Ni (CH SH, HCI (R) (X) (Y) →(Z) (ii) Nal acetone Gv) dil. H,SO, Total stable conformation possible for Z is 3. O x will give red color with cerric ammonium nitrate. Y will give white non crystalline product with aq. NAHSO3

2-Bromo pentane on reaction with NaOH, produces two structural alkene P(81%) and Q(19%). If more stable form of P is 'R' alkene. Then for the following sequence, which of the following statements is CORRECT : 6) Br, H,0 (H)HBu ĆCI, 1)NaOH/I, (1)B-H, -THF Gi1) PCC,CH;CI, (1) Buli (ii) CH,I iv)H,/Raney Ni (CH SH, HCI (R) (X) (Y) →(Z) (ii) Nal acetone Gv) dil. H,SO, Total stable conformation possible for Z is 3. O x will give red color with cerric ammonium nitrate. Y will give white non crystalline product with aq. NAHSO3

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter10: Alcohols

Section: Chapter Questions

Problem 10.52P: Alcohols are important for organic synthesis, especially in situations involving alkenes. The...

See similar textbooks

Similar questions

Chemistry Give the products of the reaction of 1 mole of 2-methy1-1,3-pentadiene with 1 mole of HBr. Whichproduct(s) will predominate if the reaction is under kinetic control? Which products) will predominateif the reaction is under thermodynamic control?
A chemist allows some pure (2S,3R)-3-bromo-2,3-diphenylpentane to react with a solution of sodium ethoxide(NaOCH2CH3) in ethanol. The products are two alkenes: A (cis-trans mixture) and B, a single pure isomer. Under thesame conditions, the reaction of (2S,3S)-3-bromo-2,3-diphenylpentane gives two alkenes, A (cis-trans mixture) and C.Upon catalytic hydrogenation, all three of these alkenes (A, B, and C) give 2,3-diphenylpentane. Determine the structuresof A, B, and C; give equations for their formation; and explain the stereospecificity of these reactions
Benzene is one of the compounds used as octane enhancers in unleaded gasoline. It is manufactured by thecatalytic conversion of acetylene to benzene: 3C2 H2(g) ⇌ C6 H6(g). Which value of Kc would make this reactionmost useful commercially? Kc ≈ 0.01, Kc ≈ 1, or Kc ≈ 10. Explain your answer
Alcohols are important for organic synthesis, especially in situations involving alkenes. The alcohol might be the desired product, or the OH group might be transformed into another functional group via halogenation, oxidation, or perhaps conversion to a sulfonic ester derivative. Formation of an alcohol from an alkene is particularly powerful because conditions can be chosen to produce either the Markovnikov or non-Markovnikov product from an unsymmetrical alkene. Using your reaction roadmap as a guide, show how to convert 4-methyl-1-pentene into 5-methylhexanenitrile. You must use 4-methyl-1-pentene and sodium cyanide as the source of all carbon atoms in the target molecule. Show all reagents needed and all molecules synthesized along the way.
Cembrene, C20H32, is a diterpenoid hydrocarbon isolated from pine resin. Cembrene has a UV absorption at 245 nm, but dihydrocembrene (C20H34), the product of hydrogenation with 1 equivalent of H2, has no UV absorption. On exhaustive hydrogenation, 4 equivalents of H2 react, and octahydrocembrene, C20H40, is produced. On ozonolysis of cembrene, followed by treatment of the ozonide with zinc, four carbonylcontaining products are obtained: Propose a structure for cembrene that is consistent with its formation from geranylgeranyl diphosphate.
Most methods of making alkenes yield predominately the more stable isomer, usually the trans. Outline all steps in the conversion of a mixture of 75% trans-2-pentene and 25% cis-2-pentene into essentially pure cis-2-pentene.
4 what is the ftir interpretation of 1-chloro-1-methylcyclohexane?
Tunicates are marine animals that are called "sea squirts" because when they are taken out of water, they tend to contract and expel seawater. Lepadiformine is a cytotoxic agent (toxic to cells) isolated from a marine tunicate. During a recent synthesis of lepadiformine, the investigators observed the formation of an interesting by-product (3) while treating diol 1 with a reagent similar in function to PBr3 (J. Org. Chem. 2012, 77, 3390–3400):
1)Chemistry students are taking an experimental course in organic chemistry at a public university. During an experiment involving conjugated dienes, some doubts arose when discussing the results obtained so far: (a) A student obtained two products from the reaction of 1,3-cyclohexadiene with Br2. His lab partner was surprised to get only one product from the reaction of 1,3 - cyclohexadiene with HBr. Explain these distinct results. (b) One student, seeing the discussion of colleagues, commented that she obtained two distinct products when reacting 1,3,5-hexatriene with HBr, with different yields just by changing the reaction temperature. Explain the results she obtained using reaction mechanism and based on kinetic and thermodynamic control involving conjugated dienes.
How many degrees of unsaturation (double bond equivalents) does C4H10ClNO have?
please provide the machanisms of 1a, 1e, 1f
Q3. For the following reactions, predict the products, mechanism and name all the products obtained Catalytic hydrogenation of cycloalkenes. Reduction of cyclohexanone with Zinc amalgam (Zn/Hg alloy) in concentrated hydrochloric acid Addition of CH2I2 in an alkene in the presence of Zn-Cu 2-hexene + chlorine gas Halogenation of cyclohexane in the presence of light and catalyst Sulfonation of Cyclobutane with oleum Addition of HBr to methylcyclopropane