2- Cis-trans isomerism in alkenes is due to a- free rotation about the double bond c- free rotation about single bond c- Zaitsev organization d- H-bonding b- restricted rotation about the double bond d- chiral carbon
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- Question: In the context of molecular orbital theory, explain the difference between the relative stability of cyclooctatetraene and benzene, as well as the factors that contribute to the exceptional stability of benzene.Ethylene glycol is unusual in that the gauche conformation is more stable than the anti conformation. Offer an explanation.Explain single bond rotation and different conformation of butane with stability order. Provide examples.
- The allotrope of carbon known as fullerenes (aka "buckyballs") has a structure best described asThe allotrope of carbon known as fullerenes (aka "buckyballs") has a structure best described asThree dimensional network of carbon atoms joined by single bondsClosed cage structure with sides consisting of 5- and 6-membered rings with alternating double and single bonds.Chain of carbon atoms with alternating double and single bonds.Flat molecule consisting of fused 6-membered rings with alternating double and single bondsShapeless jumble of free carbon atoms.Molecular Models in Dichloropropane, Butane,Chlorobutane,Dichlorocyclopropane,DichloroetheneChiral compounds have a so-called asymmetric carbon atom in the molecular structure, and are opticalactive. Study the following organic molecule containing two −? − ? – groups (thiol) andwhich is a medicine against various types of metal poisoning, including against arsenic, mercury and lead: Image Based on this skeletal structure, judge whether this molecule is chiral. Give reasons for your answer.Suggest an IUPAC name for the molecule that takes into account all the given functional groups.
- IUPAC of Alkenes and Alkynes including stereochemistryArrange according to melting temperature (highest to lowest). Arrange according to the tendency to solidify first as the temperature drops (slowest to fastest) Arrange according to the degree of unsaturation (highest to lowest). Which of the following has the highest iodine content? Which of the following has the lowest melting point? Which of the following requires the fewest moles of hydrogen for complete hydrogenation? Which of these is likely to be solid at room temperature?Draw Newman projections for the anti, eclipsed, gauche and fully eclipsed conformations of Butane. Indicate their relative stabilities and the reasons for your ranking-need to discuss the stresses involved in each case. Using suitable specific conformers of specific structures as examples, explain the difference between (a) angle strain (b) torsional strain and (c) steric strain. Need to draw the confomers and structures 4) Draw the most stable conformers using chair structures of the following: (c) cis-1,2-Dibromocyclohexane (d) trans-1,2-Dibromocyclohexane (e) cis-Decalin (f) trans-Decalin . Draw the most stable conformers of trans-1-Bromo-4-methylcyclohexane and cis-1-Bromo-4-methylcyclohexane. Which is more stable? Explain the reason for your answer. Need to include a discussion of 1,3-Diaxial interaction
- Measure the C-C-C and C-C-H bond angles in the energy-minimized model of cyclohexene and compare them with those predicted by VSEPR. Explain any differences.Refer to the equation below to answer questionsWhat is the expected arrangement of the bromine atoms relative to each other among the carbon involvedin pi bonding?A. anti-conformationB. syn-conformationC. trans-configurationD. cis-configurationIn 1935, J. Bredt, a German chemist, proposed that a bicycloalkene could not have a double bond at a bridgehead carbon unless one of the rings contains at least eight carbons. This is known as Bredt’s rule. Explain why there cannot be a double bond at this position.