2. Compare SANS and SAXS and NMR techniques determining polymer chain structure, which onerequires dissolving the polymer in a dilute solution.

SANS, SAXS, and NMR are important spectroscopic techniques that are used in the chemical analysis of…

Answered: 2. Compare SANS and SAXS and NMR…

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter22: Organic Chemistry And Biochemistry

Section: Chapter Questions

Problem 9QE

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Some natural proteins are rich in disulfide bonds, and their mechanical properties (tensile strength, viscosity, hardness, etc.) are correlated with the degree of disulfide bonding. (a) Glutenin, a wheat protein rich in disulfide bonds, is responsible for the cohesive and elastic character of dough made from wheat flour. Similarly, the hard, tough nature oftortoise shell is due to the extensive disulfide bonding in its α-keratin. What is the molecular basis for the correlation between disulfide-bond content and mechanical properties of the protein?(b) Most globular proteins are denatured and lose their activity when briefly heated to 65 °C. However, globular proteins that contain multiple disulfide bonds often must be heated longer at higher temperatures to denature them. One such protein is bovine pancreatic trypsin inhibitor (BPTI), which has 58 amino acid residues in a single chain andcontains three disulfide bonds. On cooling a solution of denatured BPTI, the activity of the…

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2. Compare SANS and SAXS and NMR techniques determining polymer chain structure, which one requires dissolving the polymer in a dilute solution.