2.1 Give the structure of Compound A OMe NaOMe 2.2 Provide a reasonable arrow pushing mechanism for the reaction in 2.1 2.3 Provide the product of the following reaction: Compound A Compound A NaOMe
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- Compound K, L and M are three isomers with the molecular formula C5H10O.Compound K cannot be oxidized, while compound M and L can be oxidized.Oxidation of compound L with hot acidified potassium permanganate,KMnO4 solution yields 2-methylbutanoic acid. When treated with Iodoformreagent, yellow precipitation only occurs in compound K. Fehling test onlyyielded positive results for compound L and negative for compound M andK. Compound M is then reacted with hydrogen chloride, HCl produceschlorocyclopentane (i) Draw the structural formula of compounds K, L and M.Compound K, L and M are three isomers with the molecular formula C5H10O.Compound K cannot be oxidized, while compound M and L can be oxidized.Oxidation of compound L with hot acidified potassium permanganate,KMnO4 solution yields 2-methylbutanoic acid. When treated with Iodoformreagent, yellow precipitation only occurs in compound K. Fehling test onlyyielded positive results for compound L and negative for compound M andK. Compound M is then reacted with hydrogen chloride, HCl produceschlorocyclopentane. (ii) Name the type of chemical reaction of compound M when reacted withhydrogen chloride, HCl .(−)-Hyoscyamine, an optically active drug used to treat gastrointestinal disorders, is isolated from Atropa belladonna, the deadly nightshade plant, by a basic aqueous extraction procedure. If too much base is used during isolation, optically inactive material is isolated. (a) Explain this result by drawing a stepwise mechanism. (b) Explain why littorine, an isomerisolated from the tailower plant in Australia, can be obtained optically pure regardless of the amount of base used during isolation.
- Provide a stepwise synthesis for benzyl chloride to benzoic acid. (including arrow-pushing mechanisms) Please show all the arrow pushCompare the chemical structure of compound A with that of compound B. Answer it in a detailed way. Thank You.(a) Illustrate the following name reactions by giving example :(i) Cannizzaro’s reaction(ii) Clemmensen reduction(b) An organic compound A contains 69.77% carbon, 11.63% hydrogen and rest oxygen. The molecular mass of the compound is 86. It does not reduce Tollen’s reagent but forms an addition compound with sodium hydrogen sulphite and gives positive iodoform test. On vigorous oxidation it gives ethanoic and propanoic acids. Derive the possible structure of compound A.
- Give the stepwise arrow-pushing mechanism for the following reaction to produce the product with stereochemical outcome.Provide a stepwise synthesis for benzyl chloride to benzoic acid. (including arrow-pushing mechanisms)When the nitrogen-containing aromatic heterocyclic compounds 1 and 2 are treated with HCl, only 1 forms the hydrochloride salt, whereas compound 2 is unreactive. Provide an explanation for this observed reactivity.
- Propose a curved arrow mechanism to account for the formation of compound C.Suggest curved arrow mechanism for 1 from 2 and identify compound ACompound X was soluble in water and ether, and its aqueous solution turned litmus blue. It reacted with sodium to give a gas. The compound reacted with benzenesulfonyl chloride and base to give an insoluble product, which was unchanged with acidification. It reacted with nitrous acid to give a yellow solid. Compound A could be