Give the mechanism of the compounds 23.6 Intramolecular Aldol ReactionsTreatment ofcertain dicarbonylcompounds withbase producescyclic products byintramolecularreactionCH₂CH3CH₂NaOHEthanolCH₂2,5-Hexanedione 3-Methyl-2-cyclopentenone(a 1,4-diketone)2,6-Heptanedione(a 1,5-diketone)+ H₂ONaOHEthanolCH3+ H₂O3-Methyl-2-cyclohexenone

Given reaction is aldol reaction and it is intramolecular aldol reaction. In presence of base first…

23.6 Intramolecular Aldol Reactions Treatment of certain dicarbonyl compounds with base produces cyclic products by intramolecular reaction CH₂ CH3 NaOH Ethanol CH₂ 2,5-Hexanedione 3-Methyl-2-cyclopentenone (a 1,4-diketone) 2,6-Heptanedione (a 1,5-diketone) + H₂O NaOH Ethanol CH3 + H₂O 3-Methyl-2-cyclohexenone

23.6 Intramolecular Aldol Reactions Treatment of certain dicarbonyl compounds with base produces cyclic products by intramolecular reaction CH₂ CH3 NaOH Ethanol CH₂ 2,5-Hexanedione 3-Methyl-2-cyclopentenone (a 1,4-diketone) 2,6-Heptanedione (a 1,5-diketone) + H₂O NaOH Ethanol CH3 + H₂O 3-Methyl-2-cyclohexenone

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter25: Biomolecules: Carbohydrates

Section25.SE: Something Extra

Problem 60AP

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