250200150100• (A]500.10 20 30 40 50 60 70Time(s)(sec)The graph above shows concentration change over time for the following chemical reaction:Alg)- B(g)Which of the following statements is true about this reaction?The reaction is a first-order reaction.B) if the graph is replotted with 1/[A] versus time (t), the graph will be linear.C) The halfite of this reaction is constant.The first half-life of this reaction is 20 seconds.All of the above is not trutiConcentration(M)

In this concentration vs time graph is plotted which is decreasing in a parabolic manner. Now, since…

250 200 150 100 • JAI 50 0. 10 20 30 40 50 60 70 Time(s) (sec) The graph above shows concentration change over time for the following chemical reaction: Alg) - B(g) Which of the following statements is true about this reaction? The reaction is a fiest-order reaction. If the graph is replotted with 1/[A] versus time (t), the graph will be linear. The half-life of this reaction is constant. The first half-life of this reaction is 20 seconds. All of the above is not true Concentration(M)

250 200 150 100 • JAI 50 0. 10 20 30 40 50 60 70 Time(s) (sec) The graph above shows concentration change over time for the following chemical reaction: Alg) - B(g) Which of the following statements is true about this reaction? The reaction is a fiest-order reaction. If the graph is replotted with 1/[A] versus time (t), the graph will be linear. The half-life of this reaction is constant. The first half-life of this reaction is 20 seconds. All of the above is not true Concentration(M)

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter11: Chemical Kinetics: Rates Of Reactions

Section11.3: Rate Law And Order Of Reactions

Problem 11.7PSP

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The initial rate for a reaction is equal to the slope of the tangent line at t 0 in a plot of [A] versus time. From calculus, initial rate = d[A]dt . Therefore. the differential rate law for a reaction is Rate = d[A]dt=k[A]n. Assuming you have some calculus in your background, derive the zero-, first-, and second-order integrated rate laws using the differential rate law.
Nitrosyl chloride (NOCI) decomposes to nitrogen oxide and chlorine gases. (a) Write a balanced equation using smallest whole-number coefficients for the decomposition. (b) Write an expression for the reaction rate in terms of [NOCl]. (c) The concentration of NOCl drops from 0.580 M to 0.238 M in 8.00 min. Calculate the average rate of reaction over this time interval.
Kinetics II You and a friend are working together in order to obtain as much kinetic information as possible about the reaction A(g)B(g)+C(g). One thing you know before performing the experiments is that the reaction is zero order, first order, or second order with respect to A. Your friend goes off, runs the experiment, and brings back the following graph. a After studying the curve of the graph, she declares that the reaction is second order, with a corresponding rate law of Rate = k[A]2. Judging solely on the basis of the information presented in this plot, is she correct in her statement that the reaction must be second order? Here are some data collected from her experiment: Time (s) [A] 0.0 1.0 1.0 0.14 3.0 2.5 103 5.0 4.5 105 7.0 8.3 107 b The half-life of the reaction is 0.35 s. Do these data support the reaction being second order, or is it something else? Try to reach a conclusive answer without graphing the data. c What is the rate constant for the reaction? d The mechanism for this reaction is found to be a two-step process, with intermediates X and Y. The first step of the reaction is the rate-determining step. Write a possible mechanism for the reaction. e You perform additional experiments and find that the rate constant doubles in value when you increase the temperature by 10oC. Your lab partner doesnt understand why the rate constant changes in this manner. What could you say to your partner to help her understand? Feel free to use figures and pictures as part of your explanation.
Consider the hypothetical first-order reaction 2A(g)X(g)+12Y(g)At a certain temperature, the half-life of the reaction is 19.0 min. A 1.00-L flask contains A with a partial pressure of 622 mm Hg. If the temperature is kept constant, what are the partial pressures of A, X, and Y after 42 minutes?
Make a graph of [A] versus time for zero-, first-, and second-order reactions. From these graphs, compare successive half-lives.
Sulfuryl chloride (SO2Cl2) decomposes to sulfur dioxide (SO2) and chlorine (Cl2) by reaction in the gas phase. The following pressure data were obtained when a sample containing 5.00 102 mol sulfuryl chloride was heated to 600. K in a 5.00 101-L container. Time (hours): 0.00 1.00 2.00 4.00 8.00 16.00 PSO2Cl2(atm): 4.93 4.26 3.52 2.53 1.30 0.34 Defining the rate as [SO2Cl2]t, a. determine the value of the rate constant for the decomposition of sulfuryl chloride at 600. K. b. what is the half-life of the reaction? c. what fraction of the sulfuryl chloride remains after 20.0 h?
Gaseous azomethane, CH3N=NCH3, decomposes in a first-order reaction when heated: CH3N=NCH3(g) N2(g) + C2H6(g) The rate constant for this reaction at 600 K is 0.0216 min1. If the initial quantity of azomethane in the flask is 2.00 g, how much remains after 0.0500 hour? What mass of N2 is formed in this time?
Experimental data are listed here for the reaction A 2 B. (a) Prepare a graph from these data; connect the points with a smooth line; and calculate the rate of change of [B] for each 10-second interval from 0.0 to 40.0 seconds. Does the rate of change decrease from one time interval to the next? Suggest a reason for this result. (b) How is the rate of change of [A] related to the rate of change of [B] in each time interval? Calculate the rate of change of [A] for the time interval from 10.0 to 20.0 seconds.
Experimental data are listed here for the reaction A 2 B. (a) Prepare a graph from these data; connect the points with a smooth line; and calculate the rate of change of [B] for each 10-second interval from 0.0 to 40.0 seconds. Does the rate of change decrease from one time interval to the next? Suggest a reason for this result. (b) How is the rate of change of [A] related to the rate of change of [B] in each time interval? Calculate the rate of change of [A] for the time interval from 10.0 to 20.0 seconds.
In Exercise 11.39, if the initial concentration of N2Oj is 0.100 .\1. how long will it take for the concentration to drop to 0.0100 times its original value? The decomposition of N2O5 in solution in carbon tetrachloride is a first-order reaction: 2N2O5—»4NO2 + O2 The rate constant at a given temperature is found to be 5.25 X 10-4 s-’. If the initial concentration of N2O5 is 0.200 M, what is its concentration after exactly 10 minutes have passed?

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