3) For a Cu-Au binary solid solution, at 927 K; activity coefficient - molar fraction is expressed with the following equation: (Be careful, don't use regular solution approach, use Gibbs- Duhem relation) Inycu = -3.74 X² Au a) Using the Gibbs-Duhem relation calculate the activity of gold for XAU = 0.4 composition. b) Calculate the mixing excess free energy of the solution.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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3) For a Cu-Au binary solid solution, at 927 K; activity coefficient - molar fraction is expressed
with the following equation: (Be careful, don't use regular solution approach, use Gibbs-
Duhem relation)
Inycu= -3.74 X² Au
a)
Using the Gibbs-Duhem relation calculate the activity of gold for XAU = 0.4 composition.
b) Calculate the mixing excess free energy of the solution.
Transcribed Image Text:3) For a Cu-Au binary solid solution, at 927 K; activity coefficient - molar fraction is expressed with the following equation: (Be careful, don't use regular solution approach, use Gibbs- Duhem relation) Inycu= -3.74 X² Au a) Using the Gibbs-Duhem relation calculate the activity of gold for XAU = 0.4 composition. b) Calculate the mixing excess free energy of the solution.
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