3. Prove that co(N)* and l'(N) are isometrically isomorphic.

Q: True or False: 1. The complex bisoxalatoplatinate(II) is a diamagnetic and its geometry is square…

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Q: Use the angular overlap method to calculate the metal d-orbital energies for trans-[Cr(NH4);Cl2]*.

A: trans-[Cr(NH4)3Cl2]+ it has trans-octahedral structure.NH3 group is σ donor and Cl is π donor.The…

Q: (a) An aqueous solution of Fe(NO3)3 has only a pale     color, but an aqueous solution of…

A: When a chemical compound has more than one type of energy levels, then it interacts with light. For…

Q: Tetrahedral complexes such as [FeF4]2- possess a Td symmetry, as indicated in the picture below. Use…

A: Symmetry operations and symmetry elements are two basic and important concepts in group theory. When…

Q: Use the symmetry criteria for polarity and chirality of molecules and refer to the structures of…

A: The compound which doesn't possess plane of symmetry , then this compound is considered as chiral…

Q: Which of the following statements is false? * 2nd and 3rd row d metals are generally larger in size…

A: Half filled and fully filled configuration are more stable than normal.

Q: Consider the d' electron configuration of a free ion: a) Calculate the spin multiplicity

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Q: Write the d orbital configurations and use the Tanabe-Sugano diagrams to identify the ground term of…

A: This is the concept of coordination compounds or complex compounds.

Q: Determine the complex conjugate of each of the following: a. 5e−iπ b. 16 + 54i

A: To determine the complex conjugate : Change the sign of i   (a) 5e−iπ Here the sign of i is…

Q: Q.6. (a) Compare and contrast main features of Orgel and Tanabe-Sugano diagrams. Mention the ground…

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Q: Draw the valence orbital diagram that represents the ground state of Fe.

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Q: Briefly explain how D orbitals of a transition metal ion become non degenerate

A: Splitting is main factor of non degeneracy of d-orbital due to approach of ligand to central metal…

Q: Which one of the following complexes has a spin of S = 2? A. trans-Ni(H2O)4CI2 B. [Co(CN)6]3- C.…

A: The spin of any coordination compounds depends upon the ligand field strength. A strong field ligand…

Q: By using valence bond theory and ligand field theory, prove that [Ru(OMe)2(PMe:)4] is a paramagnetic…

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Q: Why is the energy of the dxz and dyz orbitals in a square-planar complex lower than that of the dxy…

A: The "square planar geometry" contains 4 ligands attached with 1 "central metal atom". In this…

Q: How many unpaired electrons do you expect the complex (COCL,] to have if it is a tetrahedral shape?

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Q: Is the coordination compound [Co(NH3)6]Cl2 diamagneticor paramagnetic?

A: Here Co(NH3)6Cl2Oxidation State of Co is +x+0-2 = 0x=+2CO = 1s2 2s2 2p6 3s2 3p6 4s2 3d7CO+2 = 1s2…

Q: Determine the isomorphism class of the group Gal(GF(64)/GF(2)).

A: In group theory we dealt with isomorphism class, which deals with group of mathematical objects that…

Q: Select whether each of the following complexes are diamagnetic or paramagnetic: Aoct Aoct…

A: Magnetic behavior of any complex compound or ion can be determined by help of magnetic moment, which…

Q: 2.Why does   K4[NiBr6]  behave as a simple Curie paramagnet , but K2 [NiBr4] exhibit complex…

A: The spontaneous magnetization disappears at the Curie temperature, Tc.  Magnetization can still…

Q: Is magnesium paramagneic or diamagnetic and why? Is vanadium paramagneic or diamagnetic and why?

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Q: complex, CO

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Q: How many unpaired electrons do you predict for the tetrahedral[MnCl4]2 - ion?(a) 1, (b) 2, (c) 3,…

A: [MnCl4]2 - ion Electronic configuration - [Ar] 3d5

Q: Which of the following has the maximum number of unpaired electrons? ans. Cot Cr+ Cut Mn+

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Q: If one mole of PtCl4-5NH3 reacts with AgNO, to produce three moles of AgCl(s), how can the formula…

A: The molecular formula of the given coordination compound is = PtCl4.5NH3 The coordination sphere in…

Q: Using valence bond theory, explain the following in relation to the complex given below [Cr (CO)6]…

A: VSEPR theory is Valence Shell Electron Pair Repulsion theory.  It helps to find out the…

Q: [Rh(en)3]^3+, Rh^0: [Kr] 5s24d7 Illustrate the orbital splitting diagram for the complex.

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Q: Ca[Mo(CN)2(C2O4)(en)]2 coordination compound name

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Q: K3 [Cr (C2O4) 3] .3H2O effective atomic number of the complex. Blank 1. Fill in the blanks, read the…

A: Complex compound follow EAN rule  increase the stability.

Q: A3- Draw all the possible geometrical isomers for the complex [Cr(en)2(CN)2]. And show how could you…

A: Here we are required to find the geometrical isomer for the given complex.

Q: Two coordination sphere isomers for MnCl3(CN)3

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Q: 1. Explain why both cis and trans isomers are possible for [Co(NH3)2(C;O4)2] but only the cis isomer…

A: Since you have asked multiple question, we will solve the first question for you. If you want any…

Q: Mn^2+orbital filling diagram

A: The distribution of electrons of an element in the orbitals is termed as its electronic…

Q: Which type of substance is attracted by a magnetic field, a diamagnetic substance or a paramagnetic…

A: Paramagnetic compounds are compounds with unpaired electrons in their outermost shell.  Diamagnetic…

Q: The ion M 2+ has 3 unpaired 3d electrons in the ground state.  If M is in the first row of the…

A: The two metals ions are  V+2 and Co+2  , i.e vanadium ion and cobalt ion.

Q: Chemistry Which electron configuration represents a transition element? Group of answer choices…

A: The d-block element are called as a transition elements.

Q: cl CI N=

A: The group of symmetry components found in a molecule is referred to as a point group.

Q: 4. Consider the tetrahedral complex Ni(CO)a, see structure below A. Determine the symmetry of all…

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Q: Give an example of coordination isomerism.

A: Coordination isomerism In this isomerism, if the coordination compound contain cation as well as…

Q: 15. In 1844, cis- and trans-[PtCl2(NH3)2] were discovered. The FDA approved the anti-cancer drug…

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Q: Illustrate all possible stereoisomer geometries for the coordination compound, K[Cr(C204)2(H2O)2].

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Q: What is magnetic susceptibility and magnetic moment? Use electron configuration to describe the…

A: The interaction of electrons and nuclei with the externally applied magnetic field creates the…

Q: Choose all of the following that would be paramagnetic.     Cu+     Zn     Cr3+     Sc…

A: For given elements and ions: If there would  be unpaired electrons then it would be  paramagnetic

Q: Crystals of hydrated chromium(III) chloride are green, have an empirical formula of CrCl3 . 6 H2O,…

A: Given data contains, Empirical formula of hydrated chromium(III) chloride is CrCl3.6H2O. Octahedral…

Q: For the complex [Pt(NH3)2(H2O)2](NO3)2 draw the d-orbital splitting diagram for platinum (Pt) (low…

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Q: NO2 NO2 NO2 py-Pt-CI H3N-Pt-CI ру — Pt —NH3 NH3 ру CI А B C Show how these isomers will be…

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Q: prove that transition metals have 14 valence orbitals

A: Concept introduction: Valence electron: The sum of electrons present in outermost shell, in other…