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- 2 Draw structures to correspond with the following common and systematic names:(a) phenyl formate (b) cyclohexyl benzoate (c) cyclopentyl phenylacetate(d) N-butylacetamide (e) N,N-dimethylformamide (f) benzoic propionic anhydride(g) benzamide (h) g-hydroxyvaleronitrile (i) a-bromobutyryl chloride(j) b@butyrolactone (k) phenyl isocyanate (l) cyclobutyl ethyl carbonate(m) d@caprolactam (n) trichloroacetic anhydride (o) ethyl N-methyl carbamateWhich of the following substituent is an ortho/para-directing deactivator? a amino group b halogen group c phenyl group d carboxyl group4. what is the mechanism for this reductive amination reaction?
- Which of the following Phase 2 reactions is likely to target a N-bearing functional group specifically? a Acetylation b Glycine conjugation c Glucuronic acid conjugation d SulfationThe following scheme shows the retrosynthetic analysis of 1-isopentylaziridine to form series of intermediates via Functional Group Inversion (FGI). Choose the correct reagents of N-S for the respective conversionRank the following compounds in order of increasing basicity: I. p-nitroaniline III. N-methylaniline II. p-aminobenzaldehyde IV. p-methylaniline
- Which of the compounds shown in Image 9, on reaction with aqueous sodium hydroxide, yields sodium butanoate, CH3CH2CH2CO2Na, at the slowest rate?4. What problem(s) might occur if we make the following changes to the work-up procedure of our Ionone synthesis? a) Omit the washing with water before washing with saturated sodium bicarbonate. b) Omit the washing with brine.Place the binders below in descending order of acidity (pi) and justify your choice: CH3CN; (C2H5)2O; PCl3; As(C6H5)3; (C2H5)3N
- Predict the products obtained from the reaction of triolein with the following reagents.(a) NaOH in water (b) H2 and a nickel catalyst (c) Br2 in CCl4(d) ozone, then dimethyl sulfide (e) warm KMnO4 in water (f) CH2I2>Zn(Cu)What must be the starting material to carry out the following reaction? a) butanamide b) 4-aminobutanol c) 1-amino-2-butanone d) propanamide e) butanenitrilePredict the chemical name of compound B a. p-chlorobenzylamine b. 4-bromoaniline c. benzylamine d. p-chloronitrile e. p-chlorobenzaldehyde 2. What is the reaction name for the chemical transformation of A to B a. reductive amination b. catalytic reduction c. carbonyl dehydration d. Hofmann elimination e. Aldehyde rearrangement