4. The following reaction scheme shows the radical polymerization of styrene to make polystyrene. a) Add electron-pushing arrows to show the mechanisms of steps 1-3. Determine if these are init propagation, or termination steps. b) Radical polymerization is often performed in the absence of O2 because the oxygen radical can coupl the polymer radical to terminate polymerization. Propose electron-pushing arrows for step 4 and pred product of that step. hv

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter29: Organic Polymer Chemistry
Section: Chapter Questions
Problem 29.34P: Radical polymerization of styrene gives a linear polymer. Radical polymerization of a mixture of...
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4. The following reaction scheme shows the radical polymerization of styrene to make polystyrene.
a) Add electron-pushing arrows to show the mechanisms of steps 1-3. Determine if these are initiation,
propagation, or termination steps.
b) Radical polymerization is often performed in the absence of O2 because the oxygen radical can couple with
the polymer radical to terminate polymerization. Propose electron-pushing arrows for step 4 and predict the
product of that step.
1
hv
3
BzO
Bzof
*0-0°
step 3 keeps happening
until a termination step
4
OCcurs
2.
Transcribed Image Text:4. The following reaction scheme shows the radical polymerization of styrene to make polystyrene. a) Add electron-pushing arrows to show the mechanisms of steps 1-3. Determine if these are initiation, propagation, or termination steps. b) Radical polymerization is often performed in the absence of O2 because the oxygen radical can couple with the polymer radical to terminate polymerization. Propose electron-pushing arrows for step 4 and predict the product of that step. 1 hv 3 BzO Bzof *0-0° step 3 keeps happening until a termination step 4 OCcurs 2.
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