4. Using the equations 2 Fe (s) + 3 Cl₂ (g) → 2 FeCl₃ (s) ∆H° = -800.0 kJ/mol Si(s) + 2 Cl₂ (g) → SiCl₄ (s) ∆H° = -640.1 kJ/mol Determine the molar enthalpy (in kJ/mol) for the reaction 3 SiCl₄ (s) + 4 Fe (s) → 4 FeCl₃ (s) + 3 Si (s) 5. Using the equations 2 Sr(s) + O₂ (g) → 2 SrO (s) ∆H° = -1184 kJ/mol CO₂ (g) → C (s) + O₂ (g) ∆H° = 394 kJ/mol Determine the molar enthalpy (in kJ/mol) for the reaction C(s) + 2 SrO(s) → CO₂ (g) + 2 Sr(s).
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
4. Using the equations 2 Fe (s) + 3 Cl₂ (g) → 2 FeCl₃ (s) ∆H° = -800.0 kJ/mol Si(s) + 2 Cl₂ (g) → SiCl₄ (s) ∆H° = -640.1 kJ/mol Determine the molar enthalpy (in kJ/mol) for the reaction 3 SiCl₄ (s) + 4 Fe (s) → 4 FeCl₃ (s) + 3 Si (s)
5. Using the equations 2 Sr(s) + O₂ (g) → 2 SrO (s) ∆H° = -1184 kJ/mol CO₂ (g) → C (s) + O₂ (g) ∆H° = 394 kJ/mol Determine the molar enthalpy (in kJ/mol) for the reaction C(s) + 2 SrO(s) → CO₂ (g) + 2 Sr(s).
6. What quantity of heat (in kJ) will be released (∆H) if 0.4501 mol of NH₃ are mixed with 0.200 mol of O₂ in the following
7. Using the equations N₂ (g) + 3 H₂ (g) → 2 NH₃ (g) ∆H° = -91.8 kJ/mol C(s) + 2 H₂ (g) → CH₄ (g) ∆H° = -74.9 kJ/mol H₂ (g) + 2 C(s) + N₂ (g) → 2 HCN (g) ∆H° = 270.3 kJ/mol Determine the enthalpy (in kJ/mol) for the reaction CH₄ (g) + NH₃ (g) → HCN (g) + 3 H₂ (g).
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