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- 11.(a) 10.06 cm3 of the stock 0.100 mol dm–3 solution of NaOH was required to fully neutralise 49.5 mg of a diprotic acid (H2A). Write a balanced equation for this reaction and hence determine the molar mass (Mr) of the acid. (b) Determine the pH of 0.100 mol dm–3 NaOH at 298 K [pKw = 14.0].A particular solution is 0.05M with respect to ethanoic acid and 0.2M with respect to sodium ethanoate (Ka for ethanoic acid = 2 x 10-5moldm-3). What is this type of solution called? Calculate the pH of the solutionDetermine the pH of (a) a 0.40 M CH3COOH solution and (b) a solution that is 0.40 M CH3COOH and 0.20 M CH3 Ka for CH3COOH = 1.8 X 10-5. Could you have predicted that the pH would rise after addition of sodium acetate to pure 0.40 M acetic acid from part (a) by applying Le Chatelier’s principle?
- The acid-dissociation constant for benzoic acid (C6H5COOH) is 6.3×10−5. Part A Calculate the equilibrium concentration of H3O+ in the solution if the initial concentration of C6H5COOH is 0.060 M . Express your answer using two significant figures. part B Calculate the equilibrium concentration of C6H5COO−C6H5COO− in the solution if the initial concentration of C6H5COOHC6H5COOH is 0.060 MM . Express your answer using two significant figures.A particular solution is 0.05M with respect to ethanoic acid and 0.2M with respect to sodium ethanoate (Ka for ethanoic acid = 2 x 10-5moldm-3). What will be the effect on the pH of the solution when one or two drops of 0.1M HCl are added to 1dm3 of solution. Explain your answer.A physician wishes to prepare a buffer solution at pH = 3.82 that efficiently resists changes in pH yet contains only small concentrations of the buffering agents. Determine which one of the following weak acids, together with its sodium salt, would probably be best to use: m-chlorobenzoic acid, Ka= 1.04 × 10-4 ; p-chlorocinnamic acid, Ka=3.89 × 10-5 ; 2,5-dihydroxybenzoic acid, Ka = 1.08 ×10-3 ; or acetoacetic acid, Ka= 2.62 × 10-4 . Explain.
- a) Why can you not prepare a solution of pH = 8 by diluting sufficiently a 0.01 M solution of HCl with water? b) You could determine Ka for benzoic acid by measuring the pH of a 0.010 M solution of benzoic acid. Why is the graphical method used in this experiment a better way of determining Ka? c) List the measurements along with their uncertainties made in the determination of the molar mass of benzoic acid. Calculate the uncertainty in the mola r mass of benzoic acid determined by the titration.What is the pH of rainwater at 25°C in which atmospheric CO2 has dissolved, producing an initial [H2CO3] of 1.28×10-5 M ? Take into account the autoionization of water.The acid dissociation constant (Ka) of a 2.5 L weak acid has a value of 2.56 ×10^-4.Determine the pH of 1.0625 × 10^-2 mol of the weak acid.
- Given that the Kf for [Ni(H2O)5(NH3)]2+ is 501 and Ka for NH4+ is 2.0 x 10-5, what is the equilibrium constant for the following reaction: Ni2+(aq) + NH4+(aq) D [Ni(H2O)5(NH3)]2+ + H+(aq) In a solution of 0.010 M Ni2+ and 0.010 M NH4+, will this reaction favor products or reactants at pH=1? pH=7? pH=12?HIn(aq) + H2O(l) H3O+(aq) + In-(aq)red yellowThe acid base indicator methyl orange is red at pH values below 3 and is yellow at pH values above 6. Usingyour knowledge of pH, indicators and pKa values, predict the pKa of methyl orange.a) At temperature 25°C, 0.02 M hydrazine, N2H4 solution is 0.69% ionised. Calculate the i. Concentration of OH- ion ii. ionisation constant, Kb b) Calculate the mass of sodium benzoate, C6H5COONa that should be added to 500 mL of 0.2M aqueous benzoic acid, C6H5COOH solution to produce a buffer with pH 3.50?[ Ka for C6H5COOH = 6.3 x10-5] c) When a 1 x 10-3 moldm-3 solution of CaCl2 is mixed with an equal volume of a 1 x 10-3 moldm-3 solution of Na2SO4, will precipitate form? (Ksp CaSO4= 2 x 10-5) Do you mean that pH? That was all the given information the question gave.. I don't understand how to use the ionised part the most