7. Ammonium nitrate and sodium hydroxide react to yield ammonia, water vapor, and sodium nitrate. Calculate the enthalpy of formation of sodium hydroxide given the following heats of formation: ammonium nitrate AH°; = -230.6 kJ/mol, ammonia AH°f = -46.2 kJ/mol, water vapor AH°; = -241.8 kJ/mol, sodium nitrate AH°; = -467 kJ/mol, and AH°rn = -55.2 kJ/mol. NH,NO,(aq) + NaOH(aq) → NH:(g) + H;O(g) + NaNO;(aq)

7. Ammonium nitrate and sodium hydroxide react to yield ammonia, water vapor, and sodium nitrate. Calculate the enthalpy of formation of sodium hydroxide given the following heats of formation: ammonium nitrate AH°; = -230.6 kJ/mol, ammonia AH°f = -46.2 kJ/mol, water vapor AH°; = -241.8 kJ/mol, sodium nitrate AH°; = -467 kJ/mol, and AH°rn = -55.2 kJ/mol. NH,NO,(aq) + NaOH(aq) → NH:(g) + H;O(g) + NaNO;(aq)

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Chapter10: Entropy And The Second Law Of Thermodynamics

Section: Chapter Questions

Problem 10.97PAE

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9.50 When a 13.0-g sample of NaOH(s) dissolves in 400.0 mL of water in a coffee cup calorimeter, the temperature of the water changes from 22.6°C to 30.7C Assuming that the specific heat capacity of the solution is the same as for water, calculate (a) the heat transfer from system to surroundings and (b) H for the reaction NaOH(s)Na+(aq)+OH(aq)
When 1.0 g of fructose, C6H12O6(s), a sugar commonly found in fruits, is burned in oxygen in a bomb calorimeter, the temperature of the calorimeter increases by 1.58 C. If the heat capacity of the calorimeter and its contents is 9.90 kJ/C, what is q for this combustion?
Given 2Cr2O3(s)4Cr(s)+3O2(g)H=+2269.4kJ (a) What is the heat of formation of chromium(III) oxide? (b) What is H for the formation of 13.65 g of chromium (III) oxide?
A 5.00-g sample of aluminum pellets (specific heat capacity = 0.89 J/C g) and a 10.00-g sample of iron pellets (specific heat capacity = 0.45 J/C g) are heated to 100.0C. The mixture of hot iron and aluminum is then dropped into 97.3 g water at 22.0C. Calculate the final temperature of the metal and water mixture, assuming no heat loss to the surroundings.
9.103 One reason why the energy density of a fuel is important is that to move a vehicle one must also move its unburned fuel. Octane is a major component of gasoline. It burns according to the reaction 2C8H18(l)+25O2(g)16CO2(g)+18H2O(g) H = 1.10104 kJ Starting from this thermochemical equation, describe how you would determine the energy density, in kJ/g, for octane. Be sure to indicate what you would need to calculate or look up to complete this problem.
9.47 If 14.8 kJ of heat is given off when 1.6 g of HCl condenses from vapor to liquid, what is Hcond for this substance?
When 50.0 g of 0.200 M NaCl(aq) at 24.1 C is added to 100.0 g of 0.100 M AgNO3(aq) at 24.1 C in a calorimeter, the temperature increases to 25.2 C as AgCl(s) forms. Assuming the specific heat of the solution and products is 4.20 J/g C, calculate the approximate amount of heat in joules produced.
Calcium oxide, CaO, is prepared by heating calcium carbonate (from limestone and seashells). CaCO3(s)CaO(s)+CO2(g) Calculate the standard enthalpy of reaction, using enthalpies of formation. The Hf of CaO(s) is 635 kJ/mol. Other values are given in Table 6.2.
A sample of 0.562 g of carbon is burned in oxygen in a bomb calorimeter, producing carbon dioxide. Assume both the reactants and products are under standard state conditions, and that the heat released is directly proportional to the enthalpy of combustion of graphite. The temperature of the calorimeter increases from 26.74 C to 27.93 C. What is the heat capacity of the calorimeter and its contents?
When a 0.740-g sample of trinitrotoluene (TNT), C7H5N2O6, is burned in a bomb calorimeter, the temperature increases from 23.4 C to 26.9 C. The heat capacity of the calorimeter is 534 J/C, and it contains 675 mL of water. How much heat was produced by the combustion of the TNT sample?
Given 2Al2O3(s)4Al(s)+3O2(g)H=3351.4kJ (a) What is the heat of formation of aluminum oxide? (b) What is H for the formation of 12.50 g of aluminum oxide?
9.63 Reactions of hydrocarhons are often studied in the petroleum industry. One example is 2C3H8(g)C6H6(l)+5H2(g) , with H = 698 kJ. If 35 L of propane at 25C and 0.97 atm is to be reacted, how much heat must he supplied?

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