7. EDTA is considered as a hexadentate molecule. 8. The metal ions which are determined by direct titration with EDTA are Calcium, Magnesium and Zinc. 9. The equilibrium constant of the reaction applied to soluble complex formed is called a solubility product constant. 10. The sum of oxidation number values of all the atoms in a molecule or formula unit of a compound is equal to zero. 11. The higher is the Ks the more stable is the complex formed.

7. EDTA is considered as a hexadentate molecule. 8. The metal ions which are determined by direct titration with EDTA are Calcium, Magnesium and Zinc. 9. The equilibrium constant of the reaction applied to soluble complex formed is called a solubility product constant. 10. The sum of oxidation number values of all the atoms in a molecule or formula unit of a compound is equal to zero. 11. The higher is the Ks the more stable is the complex formed.

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter17: Electrochemistry

Section: Chapter Questions

Problem 128AE

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Similar questions

Electrochemical Cells II Consider this cell running under standard conditions: Ni(s)Ni2(aq)Cu+(aq)Cu(s) a Is this cell a voltaic or an electrolytic cell? How do you know? b Does current flow in this cell spontaneously? c What is the maximum cell potential for this cell? d Say the cell is connected to a voltmeter. Describe what you might see for an initial voltage and what voltage changes, if any, you would observe as time went by. e What is the free energy of this cell when it is first constructed? f Does the free energy of the cell change over time as the cell runs? If so, how does it change?
Using Table 17.1, calculate E° for the reaction between (a) lead and silver nitrate ion to produce lead(II) nitrate. (b) oxygen and iron(II) ions to produce water and iron(III) ions. (c) sulfur and nitrogen oxide gas in basic solution to form nitrate and sulfide ions.
Zinc is produced by electrolytic refining. The electrolytic process, which is similar to that for copper, can be represented by the two half-reactions Zn(impure,s)Zn2++2eZn2++2eZn(pure,s) For this process, a voltage of 3.0 V is used. How many kilowatt hours are needed to produce one metric ton of pure zinc?
An aqueous solution of an unknown salt of vanadium is electrolyzed by a current of 2.50 amps for 1.90 hours. The electroplating is carried out with an efficiency of 95.0%, resulting in a deposit of 2.850 g of vanadium. a How many faradays are required to deposit the vanadium? b What is the charge on the vanadium ions (based on your calculations)?
The Ostwald process for the commercial production of nitric acid involves the Following three steps: 4NH3(g)+5O2(g)4NO(g)+6H2O(s)2NO(g)+O2(g)2NO2(g)3NO2(g)+H2O(l)2HNO3(aq)+NO(g) a. Which reaction in the Ostwald process are oxidation-reduction reactions? b. Identify each oxidizing agent and reducing agent.
The iron content of hemoglobin is determined by destroying the hemoglobin molecule and producing small water-soluble ions and molecules. The iron in the aqueous solution is reduced to iron(II) ion and then titrated against potassium permanganate. In the titration, iron(ll) is oxidized to iron(III) and permanganate is reduced to manganese(II) ion. A 5.00-g sample of hemoglobin requires 32.3 mL of a 0.002100 M solution of potassium permanganate. The reaction with permanganate ion is MnO4(aq)+8H+(aq)+5Fe2+(aq)Mn2+(aq)+5Fe3+(aq)+4H2O What is the mass percent of iron in hemoglobin?
Write the equation for the reaction, if any, that occurs when each of the following experiments is performed under standard conditions. (a) Sulfur is added to mercury. (b) Manganese dioxide in acidic solution is added to liquid mercury. (c) Aluminum metal is added to a solution of potassium ions.
Substances A2, B2, and C2 can all act as oxidizing agents. In solution, A2 is green, B2 is yellow, and C2 is red. In the reactions in which they participate, they are reduced to A, B, and C ions, all of which are colorless. When a solution of C2 is mixed with one containing B ions, the color changes from red to yellow. Which species is oxidized? __________ Which is reduced? __________ When a solution of C2 is mixed with one containing A ions, the color remains red. Is C2 a better oxidizing agent than A2? __________ Is C2 a better oxidizing agent than B2? __________ Arrange A2, B2, and C2 in order of increasing strength as an oxidizing agent. ___________________ _______________ ______________ weakest oxidizing agentstrongest oxidizing agent

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