Answered: 79. Chlorine gas reacts with fluorine… | bartleby

Chemistry: An Atoms First Approach

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter8: Gases

Section: Chapter Questions

Problem 5RQ

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#79 Please solve on a sheet of paper.

79. Chlorine gas reacts with fluorine gas to form chlorine
trifluoride.
Cl2(8) + 3 F2(8) –→ 2 CIF3(8)
A 2.00-L reaction vessel, initially at 298 K, contains chlorine gas
at a partial pressure of 337 mmHg and fluorine gas at a partial
pressure of 729 mmHg. Identify the limiting reactant and deter-
mine the theoretical yield of CIF3 in grams.

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105 The decomposition of mercury(II) thiocyanate produces an odd brown snake-like mass that is so unusual the process was once used in fireworks displays. There are actually several reactions that take place when the solid Hg(SCN)2 is ignited: 2Hg(SCN)2(s)2HgS(s)+CS2(s)+C3N4(s)CS2(s)+3O2(g)CO2(g)+2SO2(g)2C3N4(s)3(CN)2(g)+N2(g)HgS(s)+O2(g)Hg(l)+SO2(g) A 42.4-g sample of Hg(SCN)2 is placed into a 2.4-L vessel at 21°C. The vessel also contains air at a pressure of 758 torr. The container is sealed and the mixture is ignited, causing the reaction sequence above to occur. Once the reaction is complete, the container is cooled back to the original temperature of 21°C. (a) Without doing numerical calculations, predict whether the final pressure in the vessel will be greater than, less than, or equal to the initial pressure. Explain your answer. (b) Calculate the final pressure and compare your result with your prediction. (Assume that the mole fraction of O2 in air is 0.21.)
94 Mining engineers often have to deal with gases when planning for the excavation of coal. Some of these gases, including methane, can be captured and used as fuel to support the mining operation. For a particular mine, 2.4 g of CH4 is present for every 100.0 g of coal that is extracted. If 45.6% of the methane can be captured and the daily production of the mine is 580 metric tons of coal, how many moles of methane could be obtained per day?
You have a gas, one of the three known phosphorus-fluorine compounds (PF3, PF3, and P2F4). To find out which, you have decided to measure its molar mass. (a) First, yon determine that the density of the gas is 5.60 g/L at a pressure of 0.971 atm and a temperature of 18.2 C. Calculate the molar mass and identify the compound. (b) To check the results from part (a), you decide to measure the molar mass based on the relative rales of effusion of the unknown gas and CO2. You find that CO2 effuses at a rate of 0.050 mol/min, whereas the unknown phosphorus fluoride effuses at a rate of 0.028 mol/min. Calculate the molar mass of the unknown gas based on these results.
93 The complete combustion of octane can be used as a model for the burning of gasoline: 2C8H18+25O216CO2+18H2O Assuming that this equation provides a reasonable model of the actual combustion process, what volume of air at 1.0 atm and 25°C must be taken into an engine to burn 1 gallon of gasoline? (The partial pressure of oxygen in air is 0.21 atm and the density of liquid octane is 0.70 g/mL.)
You have a 550.-mL tank of gas with a pressure of 1.56 atm at 24 C. You thought the gas was pure carbon monoxide gas, CO, but you later found it was contaminated by small quantities of gaseous CO2 and O2. Analysis shows that the tank pressure is 1.34 atm (at 24 C) if the CO2 is removed. Another experiment shows that 0.0870 g of O2 can be removed chemically. What are the masses of CO and CO2 in the tank, and what is the partial pressure of each of the three gases at 25 C?
Butane, C4H10, is an easily liquefied gaseous fuel. Calculate the density of butane gas at 0.857 atm and 22C. Give the answer in grams per liter
A cylinder of compressed gas is labeled Composition (mole %): 4.5% H2S, 3.0% CO2, balance N2. The pressure gauge attached to the cylinder reads 46 atm. Calculate the partial pressure of each gas, in atmospheres, in the cylinder.

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