8. Chloroform (CHCI3) is a known anesthetic. It is also uUsed to produce the refrigerant carbon tetrachloride (CCI.) according to the reaction CHCI30) + Clzia) → CCI419) + HC\19) Several experiments obtained the following data: Initial [CHCI3] (M) Initial [Cl2] (M) Initial Rate of reaction (M/s) 2.60 x 10-4 5.20 x 10-4 Experiment 0.0011 0.014 II 0.0011 0.028 II 0.0022 0.028 2.08 x 10-3 IV 0.0022 0.014 1.04 x 10-3 Write the rate law expression for the reaction. Calculate the rate constant.

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Chapter11: Chemical Kinetics
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8. Chloroform (CHCI3) is a known anesthetic. It is alsO used to produce the refrigerant
carbon tetrachloride (CCl.) according to the reaction
CHCI3(g) + Cl2ia) →CCIA(0) + HCl(g)
Several experiments obtained the following data:
Experiment
Initial [CHCI3] (M)
Initial [Cl] (M)
Initial Rate of
reaction (M/s)
2.60 x 10-4
0.0011
0.014
II
0.0011
0.028
5.20 x 10-4
II
0.0022
0.028
2.08 x 10-3
IV
0.0022
0.014
1.04 x 10-3
Write the rate law expression for the reaction. Calculate the rate constant.
Transcribed Image Text:8. Chloroform (CHCI3) is a known anesthetic. It is alsO used to produce the refrigerant carbon tetrachloride (CCl.) according to the reaction CHCI3(g) + Cl2ia) →CCIA(0) + HCl(g) Several experiments obtained the following data: Experiment Initial [CHCI3] (M) Initial [Cl] (M) Initial Rate of reaction (M/s) 2.60 x 10-4 0.0011 0.014 II 0.0011 0.028 5.20 x 10-4 II 0.0022 0.028 2.08 x 10-3 IV 0.0022 0.014 1.04 x 10-3 Write the rate law expression for the reaction. Calculate the rate constant.
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