9. Which structure represents a portion of the repeating unit for the polymer formed from cationic polymerization of methyl vinyl ether? (A) BC13 H₂O (B) (C) (D) faborat галаха n
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- List the following group of monomers in order of decreasing ability to undergo cationic polymerization.Describe how the stereoisomerism affect the degree of crystallinityof a semicrystalline polymer such as polyethyleneGive handwritten answer- Write three characteristic features for Zieglar Natta polymerization.
- When polyethylene is made by free radical polymerization, the resulting polymer has a significant amount of branching, resulting in low-density polyethylene (see Section 26.9a). When styrene undergoes free radical polymerization, on the other hand, very little branching occurs. Explain this phenomenon.Give a schematic drawing of a linear, branched and cross-linked polymer, as well as an isotactic, atactic and syndiotactic polymer.Draw a structural formula of the polymer resulting from base-catalyzed polymerization of each compound. Would you expect the polymers to be optically active? (S)-(+)-lactide is the dilactone formed from two molecules of (S)-(+)-lactic acid.
- Proteins are naturally occurring polymers formed by condensationreactions of amino acids, which have the generalstructure In this structure, — R represents — H, — CH3, or anothergroup of atoms; there are 20 different natural amino acids,and each has one of 20 different R groups. (a) Draw the generalstructure of a protein formed by condensation polymerizationof the generic amino acid shown here. (b) When only afew amino acids react to make a chain, the product is called a“peptide” rather than a protein; only when there are 50 aminoacids or more in the chain would the molecule be called a protein.For three amino acids (distinguished by having three differentR groups, R1, R2, and R3), draw the peptide that resultsfrom their condensation reactions. (c) The order in which theR groups exist in a peptide or protein has a huge influence onits biological activity. To distinguish different peptides andproteins, chemists call the first amino acid the one at the “Nterminus” and the last one the…1. Answer the following questions: (a) Why is free radical polymerization more commonly used today than ionic polymerization? (b) Almost all substituted ethylene monomers of commercial importance have the structure of CH2 = CHR or CH2 = CRR’ (where R or R' represent identical or different substituent groups). Why? (c) What are some methods for the production of conductive polymers? Give a few examples.which polymerization process is the common process in natural polymers a) Addition polymerization b) Copolymerization. c) Free radical polymerization d) Condensation polymerization
- Proteins are naturally occurring polymers formed by condensationreactions of amino acids, which have the generalstructureIn this structure, ¬R represents ¬H, ¬CH3, or anothergroup of atoms; there are 20 different natural amino acids,and each has one of 20 different R groups. (a) Draw the generalstructure of a protein formed by condensation polymerizationof the generic amino acid shown here. (b) When only afew amino acids react to make a chain, the product is called a“peptide” rather than a protein; only when there are 50 aminoacids or more in the chain would the molecule be called a protein.For three amino acids (distinguished by having three differentR groups, R1, R2, and R3), draw the peptide that resultsfrom their condensation reactions. (c) The order in which theR groups exist in a peptide or protein has a huge influence onits biological activity. To distinguish different peptides andproteins, chemists call the first amino acid the one at the “Nterminus” and the last one the one at…1. What requirement should be provided to achieve high yield and high molecular weight of polymer by condensation reaction? 2. What is interfacial polymerization 3. Describe biopolymer and synthetic polymer. Give examples to support your answer 4. Briefly discuss the classification of polymers. 5. Why polymers are widely used in our daily life?Novolac is the linear polymer which on heating with formaldehyde forms cross-linked bakelite. Write the structures of monomers and the polymer novolac.