A 15.00 mL sample of 0.355 M H3PO4 (Ka,1 7.52 × 10-3, Ka2 6.23 × 10-8, Ka,3 2.1 × 10-13) is titrated with 0.485 M NaOH. a. What is the pH of the solution after 1.50 mL of NaOH has been added? Hint: The first equivalence point has not been reached. b. What volume of NaOH is needed to reach the third equivalence point?
A 15.00 mL sample of 0.355 M H3PO4 (Ka,1 7.52 × 10-3, Ka2 6.23 × 10-8, Ka,3 2.1 × 10-13) is titrated with 0.485 M NaOH. a. What is the pH of the solution after 1.50 mL of NaOH has been added? Hint: The first equivalence point has not been reached. b. What volume of NaOH is needed to reach the third equivalence point?
Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter14: Equilibria In Acid-base Solutions
Section: Chapter Questions
Problem 74QAP: Fifty cm3 of 1.000 M nitrous acid is titrated with 0.850 M NaOH. What is the pH of the solution (a)...
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