A 3.25 g sample of an iron-containing mineral was dissolved in an acid medium and calibrated to 500 mL. A 25.00 mL aliquot was titrated with 0.0025 M KMnO4 spending a volume of 9.32 mL. Subsequently, a 25.00 mL aliquot was passed through a Walden reducer to later titrate it with the same permanganate solution, using a volume of 14.15 mL for the titration. Determine the percentage of Fe(III) in the sample and report it as % Fe2O3

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter17: Complexation And Precipitation Reactions And Titrations
Section: Chapter Questions
Problem 17.34QAP
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A 3.25 g sample of an iron-containing mineral was dissolved in an acid medium and calibrated to 500 mL. A 25.00 mL aliquot was titrated with 0.0025 M KMnO4 spending a volume of 9.32 mL. Subsequently, a 25.00 mL aliquot was passed through a Walden reducer to later titrate it with the same permanganate solution, using a volume of 14.15 mL for the titration. Determine the percentage of Fe(III) in the sample and report it as % Fe2O3
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