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- Why cis-Ru(II)Cl2(DMSO)4 reacts with pyridine, et cetera, to give substitution of the DMSO but not the chloride ligands, but trans-Ru(II)Cl2(py)4 react with suitable Na+ and K+ salts in aqueous pyridine to afford chloride-substituted derivatives. write the reactions equations.give UV-vis spectrum showing (n to pi*) transition in addition to the main one and HNMR spectrum of the product from the following reaction and explain one possible reactions by this reaction scheme.Help with the following ochem reaction scheme... Consider 3,4-dimethylpiperidine being subjected to the below reaction scheme: step 1) CH3I (excess) step 2) NaOH, heat step 3) CH3I (excess) step 4) NaOH, heat Provide the bond line structures for the major organic product obtained in each step and then discuss the regiochemistry for step 2.
- Predict the product of the following reaction and classify the reaction Pb+FeSO4---> PbSO4+ ______Please write out the mechanism for the acid (WHICH IS 3-BROMOBENZOIC ACID) reacting with anilide. PROVIDE THE MECHANISM AND BRIEFLY EXPLAIN THE STEPS OCCURING PLEASEGive the expected products of lithium aluminum hydride reduction of the followingcompounds (followed by hydrolysis).(a) butyronitrile (b) N-cyclohexylacetamide
- For each of the following mixtures of reactants, give (i) a plausible chemical equation and (ii) structurefor the organometallic product, and (iii) general reason for the course of the reaction: (a)methyllithium and W(CO)6, (b) Co2(CO)8 and AlBr3.Give the structures of the products obtained when the following are heated. Include stereochemistry where relevant.A certain hydrocarbon, C7H10, yields the two products shown below upon oxidative cleavage with KMnO4/H3O+ . Deduce the structure of the hydrocarbon.
- What is the expected product of the reaction scheme below?Organotin compounds play a significant role in diverse industrial applications. They have been used as plastic stabilizers and as pesticides or fungicides. One method used to prepare simple tetraalkylstannanes is the controlled direct reaction of liquid tin(IV) chloride with highly reactive trialkylaluminum compounds, such as liquid triethylaluminum (Al(CzHs)3). 3SnCl4 + 4Al(C2H5)3 → 3Sn(C2H5)4 + 4AlCl3 In one experiment, 0.160 L of SnCl4 (d= 2.226 g/mL) was treated with 0.346 L of triethylaluminum (Al(C2H5)3); d = 0.835 g/mL). What is the theoretical yield in this experiment (mass of tetraethylstannane, Sn(C2H5)4)? If 0.257L of tetraethylstannane (d= 1.187 g/mL) were actually isolated in this experiment, what was the percent yield?Suggest an explanation for the fact that the order of reactivity of the halides toward n-butylbrosylate in acetone is Cl” > Br” > I~ when (C4H9)4N* is the cation of the halide salt butI” > Br” > Cl” when Li’ is the cation
