A chemical engineer is studying the following reaction: CH 4(9)+2H,S(g) → CS2(9)+4H,(9) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.020. The engineer charges ("fills") four reaction vessels with methane and hydrogen sulfide, and lets the reaction begin. She then measures the composition of th mixture inside each vessel from time to time. Her first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time she measures the compositions. reaction vessel compound pressure expected change in pressure CH4 8.25 atm t increase I decrease (no change) H,S 3.44 atm t increase OI decrease (no change) Cs, 2.39 atm t increase I decrease (no change) 2.60 atm t increase I decrease O (no change) CH 8.99 atm t increase I decrease (no change)

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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A chemical engineer is studying the following reaction:
CH 4(9)+2H,S(g) -
CS 2(9)+4H2(g)
→
At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.020.
The engineer charges ("fills") four reaction vessels with methane and hydrogen sulfide, and lets the reaction begin. She then measures the composition of the
mixture inside each vessel from time to time. Her first set of measurements are shown in the table below.
Predict the changes in the compositions the engineer should expect next time she measures the compositions.
reaction
expected change in pressure
compound
pressure
vessel
CHA
8.25 atm
f increase
I decrease
(no change)
H,S
3.44 atm
f increase
I decrease
(no change)
A
Cs,
f increase
I decrease
(no change)
2.39 atm
H2
2.60 atm
f increase
I decrease
(no change)
CHA
f increase
I decrease
(no change)
8.99 atm
H,S
4.94 atm
f increase
I decrease
(no change)
Cs,
I decrease
(no change)
1.65 atm
f increase
H,
-0.40 atm
f increase
I decrease
(no change)
CH4
8.92 atm
f increase
I decrease
(no change)
H,S
4.79 atm
f increase
I decrease
(no change)
Cs,
1.72 atm
↑ increase
I decrease
(no change)
H2
-0.11 atm
↑ increase
I decrease
(no change)
B.
Transcribed Image Text:A chemical engineer is studying the following reaction: CH 4(9)+2H,S(g) - CS 2(9)+4H2(g) → At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.020. The engineer charges ("fills") four reaction vessels with methane and hydrogen sulfide, and lets the reaction begin. She then measures the composition of the mixture inside each vessel from time to time. Her first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time she measures the compositions. reaction expected change in pressure compound pressure vessel CHA 8.25 atm f increase I decrease (no change) H,S 3.44 atm f increase I decrease (no change) A Cs, f increase I decrease (no change) 2.39 atm H2 2.60 atm f increase I decrease (no change) CHA f increase I decrease (no change) 8.99 atm H,S 4.94 atm f increase I decrease (no change) Cs, I decrease (no change) 1.65 atm f increase H, -0.40 atm f increase I decrease (no change) CH4 8.92 atm f increase I decrease (no change) H,S 4.79 atm f increase I decrease (no change) Cs, 1.72 atm ↑ increase I decrease (no change) H2 -0.11 atm ↑ increase I decrease (no change) B.
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