A container with insulating walls is divided into two equal parts by a partition fitted with a valve. One part is filled with an ideal gas at a pressure P and temperature T, whereas the other part is completely evacuated. If the valve is suddenly opened, the pressure and temperature of the gas will be P T (b) 2 2 (a) ,T (c) P, T T. (d) P,

A container with insulating walls is divided into two equal parts by a partition fitted with a valve. One part is filled with an ideal gas at a pressure P and temperature T, whereas the other part is completely evacuated. If the valve is suddenly opened, the pressure and temperature of the gas will be P T (b) 2 2 (a) ,T (c) P, T T. (d) P,

University Physics Volume 2

18th Edition

ISBN:9781938168161

Author:OpenStax

Publisher:OpenStax

Chapter3: The First Law Of Thermodynamics

Section: Chapter Questions

Problem 56P: Consider a cylinder with a movable piston containing n moles of an ideal gas. The entire apparatus...

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An aluminum rod 0.500 m in length and with a cross-sectional area of 2.50 cm2 is inserted into a thermally insulated vessel containing liquid helium at 4.20 K. The rod is initially at 300 K. (a) If one-half of the rod is inserted into the helium, how many liters of helium boil off by the time the inserted half cools to 4.20 K? Assume the upper half does not yet cool. (b) If the circular surface of the upper end of the rod is maintained at 300 K, what is the approximate boil-off rate of liquid helium in liters per second after the lower half has reached 4.20 K? (Aluminum has thermal conductivity of 3 100 W/m K at 4.20 K; ignore its temperature variation. The density of liquid helium is 125 kg/m3.)
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Two moles of nitrogen gas, with =7/5 for ideal diatomic gases, occupies a volume of 102 m3 in an insulated cylinder at temperature 300 K. The gas is adiabatically and reversibly compressed to a volume of 5 L. The piston of the cylinder is locked in its place, and the insulation around the cylinder is removed. The heat-conducting cylinder is then placed in a 300-K bath. Heat from the compressed gas leaves the gas, and the temperature of the gas becomes 300 K again. The gas is then slowly expanded at the fixed temperature 300 K until the volume of the gas becomes 102 m3, thus making a complete cycle for the gas. For the entire cycle, calculate (a) the work done by the gas, (b) the heat into or out of the gas, (c) the change in the internal energy of the gas, and (d) the change in entropy of the gas.
A sample of a monatomic ideal gas occupies 5.00 L at atmospheric pressure and 300 K (point A in Fig. P17.68). It is warmed at constant volume to 3.00 atm (point B). Then it is allowed to expand isothermally to 1.00 atm (point C) and at last compressed isobarically to its original state. (a) Find the number of moles in the sample. Find (b) the temperature at point B, (c) the temperature at point C, and (d) the volume at point C. (e) Now consider the processes A B, B C, and C A. Describe how to carry out each process experimentally. (f) Find Q, W, and Eint for each of the processes. (g) For the whole cycle A B C A, find Q, W, and Eint. Figure P17.68
An amount of n moles of a monatomic ideal gas in a conducting container with a movable piston is placed in a large thermal heat bath at temperature T1 and the gas is allowed to come to equilibrium. After the equilibrium is leached, the pressure on the piston is lowered so that the gas expands at constant temperature. The process is continued quasi-statically until the final pressure is 4/3 of the initial pressure p1 . (a) Find the change in the internal energy of the gas. (b) Find the work done by the gas. (c) Find the heat exchanged by the gas, and indicate, whether the gas takes in or gives up heat.
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Consider the Maxwell-Boltzmann distribution function plotted in Problem 28. For those parameters, determine the rms velocity and the most probable speed, as well as the values of f(v) for each of these values. Compare these values with the graph in Problem 28. 28. Plot the Maxwell-Boltzmann distribution function for a gas composed of nitrogen molecules (N2) at a temperature of 295 K. Identify the points on the curve that have a value of half the maximum value. Estimate these speeds, which represent the range of speeds most of the molecules are likely to have. The mass of a nitrogen molecule is 4.68 1026 kg. Equation 20.18 can be used to find the rms velocity given the temperature, Boltzmanns constant, and the mass of the atom or molecule. The mass of a nitrogen molecule is 4.68 1026 kg. vrms=3kBTm=3(1.381023J/K)4.681026kg=511m/s Using the results of Problem 28 and the rms velocity, we can calculate the value of f(v). f(vrms) = (3.11 108)(511)2 e(5.75106(511)2) = 0.00181 The most probable speed, for which this function has its maximum value, is given by Equation 20.20. vmp=2kBTm=2(1.381023J/K)(295K)4.681026kg=417m/s f(vmp) = (3.11108)(417)2 e(5.75106(417)2) = 0.00199 We plot these points on the speed distribution. The most probable speed is indeed at the peak of the distribution function. Since the function is not symmetric, the rms velocity is somewhat higher than the most probable speed. Figure P20.29ANS