a) Find the value of (as/V), for the van der Waals gas. b) Derive an expression for the change in entropy for the isothermal expansion of one mole of the van der Waals gas from V₁ to V₂. c) Compare the result in (b) with the expression for the ideal gas. For the same increase in volume, will the entropy increase be greater for the van der Waals gas or for the ideal gas?

University Physics Volume 2
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Chapter4: The Second Law Of Thermodynamics
Section: Chapter Questions
Problem 83CP: (a) infinitesimal amount of heat is added reversibly to a system. By combining the first and second...
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a) Find the value of (as/V), for the van der Waals gas.
b) Derive an expression for the change in entropy for the isothermal expansion of one mole of the
van der Waals gas from V₁ to V₂. c) Compare the result in (b) with the expression for the ideal
gas. For the same increase in volume, will the entropy increase be greater for the van der Waals
gas or for the ideal gas?
Transcribed Image Text:a) Find the value of (as/V), for the van der Waals gas. b) Derive an expression for the change in entropy for the isothermal expansion of one mole of the van der Waals gas from V₁ to V₂. c) Compare the result in (b) with the expression for the ideal gas. For the same increase in volume, will the entropy increase be greater for the van der Waals gas or for the ideal gas?
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