(a) NH3 and O₂ are fed to a reactor at 25°C and at the rates of 100 mol/s and 200 mol/s respectively. The ammonia is completely consumed, according to the following reaction equation at 1 atm: 4 NH3(g) + 5 O₂ (g) → 4 NO(g) + 6 H₂O (g) In order to maintain the product gas at a temperature of 300°C, 19,700 kW of heat must be removed from the reactor. (i) Calculate the standard heat of reaction for the above reaction equation. (ii) Calculate the standard heat of reaction for NH3(g) + 5/4 O₂ (g) → NO(g) + 3/2 H₂O (g) Specific enthalpies of gas (referenced to 25°C and 1 atm): O₂ (g) at 300°C, 1 atm: 8.470 kJ/mol NO (g) at 300°C, 1 atm: 8.453 kJ/mol H₂O(g) at 300°C. 1 atm: 9.570 kJ/mol

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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(a)
NH3 and O₂ are fed to a reactor at 25°C and at the rates of 100 mol/s and 200 mol/s
respectively. The ammonia is completely consumed, according to the following reaction
equation at 1 atm:
4 NH3(g) + 5 O₂ (g) → 4 NO (g) + 6 H₂O (g)
In order to maintain the product gas at a temperature of 300°C, 19,700 kW of heat must
be removed from the reactor. (i) Calculate the standard heat of reaction for the above
reaction equation. (ii) Calculate the standard heat of reaction for
NH3 (g) + 5/4 O₂ (g) → NO (g) + 3/2 H₂O (g)
Specific enthalpies of gas (referenced to 25°C and 1 atm):
O₂ (g) at 300°C, 1 atm: 8.470 kJ/mol
NO (g) at 300°C, 1 atm: 8.453 kJ/mol
H₂O (g) at 300°C, 1 atm: 9.570 kJ/mol
Transcribed Image Text:(a) NH3 and O₂ are fed to a reactor at 25°C and at the rates of 100 mol/s and 200 mol/s respectively. The ammonia is completely consumed, according to the following reaction equation at 1 atm: 4 NH3(g) + 5 O₂ (g) → 4 NO (g) + 6 H₂O (g) In order to maintain the product gas at a temperature of 300°C, 19,700 kW of heat must be removed from the reactor. (i) Calculate the standard heat of reaction for the above reaction equation. (ii) Calculate the standard heat of reaction for NH3 (g) + 5/4 O₂ (g) → NO (g) + 3/2 H₂O (g) Specific enthalpies of gas (referenced to 25°C and 1 atm): O₂ (g) at 300°C, 1 atm: 8.470 kJ/mol NO (g) at 300°C, 1 atm: 8.453 kJ/mol H₂O (g) at 300°C, 1 atm: 9.570 kJ/mol
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