A polynomial fit to measurements of the total volume of a binary mixture of A and B is, ν = 778.55 − 22.5749x + 0.56892x 2 + 0.01023x 3 + 0.00234x 4 where ν = V/cm3 , x = nB/mol, and nB is the amount of B present. Derive an expression for the partial molar volume of B.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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A polynomial fit to measurements of the total volume of a binary mixture of A and B is, ν = 778.55 − 22.5749x + 0.56892x 2 + 0.01023x 3 + 0.00234x 4 where ν = V/cm3 , x = nB/mol, and nB is the amount of B present. Derive an expression for the partial molar volume of B.

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