A pure sample of Substance S is put into an evacuated flask. The flask is then heated steadily and the temperature measured as time passes. The results are graphed below, in the middle (in green). Identical experiments are now run on Substance Y and Substance Z. Substance Y is just like S except that it has a lower heat capacity in the gaseous phase C, (e). Substance Z is just like S except that it has a higher heat capacity in the solid phase C, (s). Select the graphs below, on the left and right, that show the results you expect for these new experiments Substance Y (lower C, (g)) (Drag the slider to choose an image) temperature (°C) Substance S added heat (kJ/mol Substance Z (higher C, (s)) (Drag the slider to choose an image)

A pure sample of Substance S is put into an evacuated flask. The flask is then heated steadily and the temperature measured as time passes. The results are graphed below, in the middle (in green). Identical experiments are now run on Substance Y and Substance Z. Substance Y is just like S except that it has a lower heat capacity in the gaseous phase C, (e). Substance Z is just like S except that it has a higher heat capacity in the solid phase C, (s). Select the graphs below, on the left and right, that show the results you expect for these new experiments Substance Y (lower C, (g)) (Drag the slider to choose an image) temperature (°C) Substance S added heat (kJ/mol Substance Z (higher C, (s)) (Drag the slider to choose an image)

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter9: Energy And Chemistry

Section: Chapter Questions

Problem 9.106PAE

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General Zod has sold Lex Luthor what Zod claims to be a new copper-colored form of kryptonite, the only substance that can harm Superman. Lex, not believing in honor among thieves, decided to carry out some tests on the supposed kryptonite. From previous tests, Lex knew that kryptonite is a metal having a specific heat capacity of 0.082 J/gC and a density of 9.2 g/cm3. Lex Luthers first experiment was an attempt to find the specific heat capacity of kryptonite. He dropped a 10 g 3 g sample of the metal into a boiling water bath at a temperature of 100.0C 0.2C. He waited until the metal had reached the bath temperature and then quickly transferred it to I 00 g 3 g of water that was contained in a calorimeter at an initial temperature of 25.0C 0.2C. The final temperature of the metal and water was 25.2C. Based on these results, is it possible to distinguish between copper and kryptonite? Explain. When Lex found that his results from the first experiment were inconclusive, he decided to determine the density of the sample. He managed to steal a better balance and determined the mass of another portion of the purported kryptonite to be 4 g 1 g. He dropped this sample into water contained in a 25-mL graduated cylinder and found that it displaced a volume of 0.42 mL 0.02 mL. Is the metal copper or kryptonite? Explain. Lex was finally forced to determine the crystal structure of the metal General Zod had given him. He found that the cubic unit cell contained four atoms and had an edge length of 600. pm. Explain how this information enabled Lex to identify the metal as copper or kryptonite. Will Lex be going after Superman with the kryptonite or seeking revenge on General Zod? What improvements could he have made in his experimental techniques to avoid performing the crystal structure determination?
hat does temperature measure? Are the molecules in a beaker of warm water moving at the same speed as the molecules in a beaker of cold water? Explain? What is heat? Is heat the same as temperature?
What quantity of heat energy must have en applied to a block of aluminum weighing 42.7 g if the temperature of the block of aluminum increased by 15.2 °C? (See Table 10.1.)
If 125 J of heat energy is applied to a block of silver weighing 29.3 g, by how many degrees will the temperature of the silver increase? (See Table 10.1.)
The first step in the preparation of lead from its ore (galena, PbS) consists of roasting the ore. PbS(s)+32O2(g)SO2(g)+PbO(s) Calculate the standard enthalpy change for this reaction, using enthalpies of formation (see Appendix C).
How much heat is evolved when 1255 g of water condensesto a liquid at 100°C?
Which of the enthalpies of combustion in Table 5.2 the table are also standard enthalpies of formation?
You are camping and contemplating placing some hot objects into your sleeping bag to warm it. You warm a rock and a canteen of water, of roughly equal mass, around the fire. Which would be more effective in warming your sleeping bag? Why?
For the reaction HgO(s)Hg(l)+12O2(g),H=+90.7kJ: a.What quantity of heat is required to produce 1 mole of mercury by this reaction? b.What quantity of heat is required to produce 1 mole of oxygen gas by this reaction? c.What quantity of heat would be released in the following reaction as written? 2Hg(l) + O2(g) 2HgO(s)
A compound is 82.7% carbon and 17.3% hydrogen, and has a molar mass of approximately 60 g/mol. When 1.000 g of this compound burns in excess oxygen, the enthalpy change is 49.53 kJ. (a) What is the empirical formula of this compound? (b) What is the molecular formula of this compound? (c) What is the standard enthalpy of formation of this compound? (d) Two compounds that have this molecular formula appear in Appendix G. Which one was used in this exercise?
9.41 Under what conditions does the enthalpy change equal the heat of a process?
A 0.470-g sample of magnesium reacts with 200 g dilute HCl in a coffee-cup calorimeter to form MgCl2(aq) and H2(g). The temperature increases by 10.9 C as the magnesium reacts. Assume that the mixture has the same specific heat as water and a mass of 200 g. (a) Calculate the enthalpy change for the reaction. Is the process exothermic or endothermic? (b) Write the chemical equation and evaluate H.

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