A sample of 20 mg of 9-fluorenone is dissolved in 7 mL of diethyl ether. The resulting organic solution is extracted with 18 mL of water. Assuming the Kp for 9-fluorenone in diethyl ether/ water is 9.5, how much 9-fluorenone would remain in the ether layer? Type your numeric answer and submit
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![A sample of 20 mg of 9-fluorenone is dissolved in 7 mL of diethyl ether. The resulting organic solution is extracted with 18 mL of
water. Assuming the Kp for 9-fluorenone in diethyl ether/ water is 9.5, how much 9-fluorenone would remain in the ether layer?
Type your numeric answer and submit
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- A student dissolved 4 drops of an unknown compound in 1 mL of methylene chloride (dichloromethane) in a test tube. They added 5 drops of a 2% solution of bromine in dichloromethane dropwise and mixed the contents within the test tube gently. They observed the red-brown color discharges (turns colorless) until the last drop. What compound is most likely the unknown? ©GMU 2020 Oa. Methanol b. Cyclohexane c. n-Butyl Bromide O d. Hex-2-ene COLE QUESTION 6 A student placed 2 drops of an unknown sample in a test tube and added 2 mL of ethanol to the test tube while mixing gently. They added 2 drops of potassium permanganate reagent to the test tube and mixed the contents of the test tube gently. The initial color was a deep purple but then changed to a yellow color which precipitates as a brown solid. What compound is most likely the unknown? OGMU 2020 a. Cyclopentane O b. Cyclohexene c. 1-Pentyl Chloride d. 2-Propanol SOUL QUESTION 7 A student performed the Beilstein test within a chemical…Suppose that a student extracted the ether solution first with aqueous 1 M KOH and then afterwards with aqueous K2HPO4. How would this affect the apparent yields and the purity of the aspirin and the acetaminophen? Justify your answer by showing pertinent reaction equations, and K values for each reaction. (Hint: you should have a reaction equation for each of the following: aspirin with K2HPO4, acetaminophen with K2HPO4, aspirin with KOH, and acetaminophen with Кон.Question 4. phthalate and dibutyl phthalate in an inert solvent like chloroform. Both steps of this reaction rapidly establish equilibrium. In this system, would you expect adding an equimolar amount of one reagent dropwise to the other to affect the outcome of the reaction? Explain your response. Consider the acid-catalyzed esterification of phthalic acid to form buthyl (K =~1.0) H* .COOH H20 но CHCI3 СООН СООН phthalic acid butanol butyl phthalate (K=~1.0) H* но + H20 CHCI3 `COOH butyl phthalate butanol dibutyl phthalate O=U O=0 0=C
- What is the theoretical yield of T-butyl chloride formation from 12.4 mL T-butyl alcohol, 49 mL HCL? Please don't provide handwritten solution7. Consider the crystallization of sulfanilamide from 95% ethyl alcohol. If impure sulfanilamide is dissolved in the minimum amount of 95% ethyl alcohol at 40°C rather than 78°C (the boiling point of ethyl alcohol), how would this affect the percent recovery of pure sulfanilamide? Explain your answer.Table 1. Solubility Tests. Functional Group Observations (specify type if any) Sample in concentrated (+/-) H2SO4 Color orange Hydroxyl group Hydroxyl group Hydroxyl group 1-butanol Color orange 2-butanol Color orange diisopropyl ether Look at the structures of compounds tested for solubility in concentrated H2SO4. What generalization can be made for a substance to be soluble in concentrated H2SO4 ?
- What is the Kc expression for the following reaction? 2 NO2(g) + H2O(1) --> HNO2(aq) + HNOglaq) [[HNO2(aq)] [HNOglaq)] [NO2(g)]^2 OHNO,(aq)] [HNO3(aq)] [NO2(g)]^2 (H20(10) (HNO2(aq)) [HNOglaq)] 2 [NO2(g]]^2 [H2O(1) [HNO2(aq)) + [HNO3laq)] 2 INO2(g)] + [H20()]Will dilute sulfuric acid also be able to precipitate benzoic acid from a solution of sodium benzoate? * A- Yes B- No5. Give the definition of the inductive effect. What is the reason for its appearance in the molecule? Show the effect of the inductive effect in molecules: bromoethane CH3CH3B1; ethanol CH3CH2OH; fluoroethane CH3CH2F.
- You were given a mixture of two miscible solvent A and B that you are tasked to separate. You know that solvent A has a boiling point of 49 oC while solvent B has a boiling point of 174 oC. Which of the listed method would overall be the most efficient? Fractional distillation Recrystallization Solid-liquid extraction Liquid-liquid extraction Simple distillation Acid-Base extractionDetermine the values of Kc that correspond to the following values of Kp. 1.) SO2CI2(g)—›‹—SO2(g)+CI2(g) Kp=2.9×10^-2 at 303K 2.) 2 NO2(g)—›‹— 2 NO(g)+O2(g) Kp=0.275 at 700k 3.) CO(g)+CI2(g)—›‹—COCI2(g) Kp=22.5The followings methods are useful to induce crystallization EXCEPT adding a small crystal of the desired compound, called a seed crystal, to the solution adding anhydrous potassium carbonate to the solution and cooling it in an ice bath scratching the inner wall of the Erlenmeyer flask with a glass stirring rod reheating the solution to boiling to boil off some of the solvent, and then allow the solution to cool to room temperature again to effect crystallization
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