A semi-permeable membrane separates the contents of cell. The concentration of sodium ions is 2molmolL'atmoutside of the cell and 2.6LLinside of the cell. The ideal gas constant R = 8.206×10and room temperature is about 20°C or 293 K.-2K-mol(a) Determine the osmotic pressure (in atm) and the tonicity of the solution surrounding a cell withradius of 0.008 mm at room temperature.П= 4.8074✓atm

Pressure outside: Tonicity: HypotonicExplanation:

Answered: A semi-permeable membrane separates the…

Physics for Scientists and Engineers: Foundations and Connections

1st Edition

ISBN:9781133939146

Author:Katz, Debora M.

Publisher:Katz, Debora M.

Chapter19: Temperature, Thermal Expansion And Gas Laws

Section: Chapter Questions

Problem 38PQ

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(a) Show that the density of an ideal gas occupying a volume V is given by = PM/KT, where M is the molar mass. (b) Determine the density of oxygen gas at atmospheric pressure and 20.0C.
One process for decaffeinating coffee uses carbon dioxide ( M=44.0 g/mol) at a molar density of about 14,0 mol/m3 and a temperature of about 60 . (a) Is CO2 a solid, liquid, gas, or supercritical fluid under those conditions? (b) The van der Waals constants for carbon dioxide are a=0.3658 Pa m6/mol2 and b=4.286105 m3/mol. Using the van der Waals equation, estimate pressure of CO2 at that temperature and density. `
The partial pressure of carbon dioxide in the lungs is about 470 Pa when the total pressure in the lungs is 1.0 atm. What percentage of the air molecules in the lungs is carbon dioxide? Compare your result to the percentage of carbon dioxide in the atmosphere, but 0.033%.
From the MaxwellBoltzmann speed distribution, show that the most probable speed of a gas molecule is given by Equation 16.23. Note: The most probable speed corresponds to the point at which the slope of the speed distribution curve dNv/dv is zero.
Consider the Maxwell-Boltzmann distribution function plotted in Problem 28. For those parameters, determine the rms velocity and the most probable speed, as well as the values of f(v) for each of these values. Compare these values with the graph in Problem 28. 28. Plot the Maxwell-Boltzmann distribution function for a gas composed of nitrogen molecules (N2) at a temperature of 295 K. Identify the points on the curve that have a value of half the maximum value. Estimate these speeds, which represent the range of speeds most of the molecules are likely to have. The mass of a nitrogen molecule is 4.68 1026 kg. Equation 20.18 can be used to find the rms velocity given the temperature, Boltzmanns constant, and the mass of the atom or molecule. The mass of a nitrogen molecule is 4.68 1026 kg. vrms=3kBTm=3(1.381023J/K)4.681026kg=511m/s Using the results of Problem 28 and the rms velocity, we can calculate the value of f(v). f(vrms) = (3.11 108)(511)2 e(5.75106(511)2) = 0.00181 The most probable speed, for which this function has its maximum value, is given by Equation 20.20. vmp=2kBTm=2(1.381023J/K)(295K)4.681026kg=417m/s f(vmp) = (3.11108)(417)2 e(5.75106(417)2) = 0.00199 We plot these points on the speed distribution. The most probable speed is indeed at the peak of the distribution function. Since the function is not symmetric, the rms velocity is somewhat higher than the most probable speed. Figure P20.29ANS
Using a numerical integration method such as Simpson's rule, find the fraction of molecules in a sample of oxygen gas at a temperature of 250 K that have speeds between 100 m/s and 150 m/s. The molar mass of oxygen (O2) is 32.0 g/mol. A precision to two significant digits is enough.
On a hot summer day, the density of air at atmospheric pressure at 35.0C is 1.1455 kg/m3. a. What is the number of moles contained in 1.00 m3 of an ideal gas at this temperature and pressure? b. Avogadros number of air molecules has a mass of 2.85 102 kg. What is the mass of 1.00 m3 of air? c. Does the value calculated in part (b) agree with the stated density of air at this temperature?
What is the gauge pressure inside a tank of 4.86104 mol of compressed nitrogen with a volume of 6.56 m3 if the rms speed is 514 m/s?
Gas is contained in an 8.00-L vessel al a temperature of 20.0C and a pressure of 9.00 atm. (a) Determine the number of moles of gas in the vessel. (b) How many molecules are in the vessel?
An ideal gas is confined to a container whose volume is fixed. If the container holds n moles of gas, by what factor will the pressure increase if the absolute temperature is increased by a factor of 2?
What pressure (in atm) would be exerted by 85 g of fluorine gas (Mm = 38 g/ mole) in a 1.50 liter vessel at -38oC?

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