Answered: a) Show a detailed mechanism for the…

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a) Show a detailed mechanism for the reaction to produce nitrogen gas and the two carbon radicals shown above.

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter8: Haloalkanes, Halogenation, And Radical Reactions

Section: Chapter Questions

Problem 8.22P: Following is a balanced equation for the allylic bromination of propene. CH2==CHCH3 + Br2 h...

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Concept explainers

Designing a Synthesis

Organic synthesis is a branch of chemical synthesis that involves the planned construction of organic compounds/molecules from smaller units that possess functional groups. Friedrich Wöhler was the first scientist who designed the synthesis of an organic compound, urea from inorganic starting materials silver cyanate with ammonium chloride via a simple, one-step synthesis.

Question

5. In the radical addition of HBr to alkenes, we saw benzoyl peroxide as a radical
initiator. The reaction below uses a different radical initiator:
HBr
.CN
NC
`N´
(radical initiator)
The reaction showing the formation of the initial radicals using this initiator is shown
below:
CN
NEN
2 х
NC
+
NC
a) Show a detailed mechanism for the reaction to produce nitrogen gas and the two
carbon radicals shown above.
b) Show how the carbon radical produced above could react with HBr to make a bromine
radical, completing the initiation step for the reaction at the top of the page.
c) Show a detailed mechanism for the propagation step of the reaction at the top of the
page and circle the major organic product produced from the reaction.

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