A solution of Na2C204 is added dropwise to a solution that is 0.0714 M in Cd2+ and 0.521 M in Ag*. (a) What concentration of C₂042 is necessary to begin precipitation? (Neglect volume changes.) [C₂04²] = M. (b) Which cation precipitates first? O Cd²+ O Ag [C₂042] = The Ksp of CdC204 is 1.42e-08. The Ksp of Ag2C₂O4 is 5.4e-12. (c) What is the concentration of C₂04² when the second cation begins to precipitate? M.

Chemistry: Principles and Reactions
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Author:William L. Masterton, Cecile N. Hurley
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Chapter15: Complex Ion And Precipitation Equilibria
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A solution of Na2C204 is added dropwise to a solution that is 0.0714 M in Cd²+ and 0.521 M in Ag+.
(a) What concentration of C₂04² is necessary to begin precipitation? (Neglect volume changes.)
[C₂04²] =
M.
(b) Which cation precipitates first?
O Cd²+
O Ag+
[C₂04²-] =
The Ksp of CdC₂04 is 1.42e-08.
The Ksp of Ag₂C₂O4 is 5.4-12.
(c) What is the concentration of C₂04² when the second cation begins to precipitate?
M.
Transcribed Image Text:A solution of Na2C204 is added dropwise to a solution that is 0.0714 M in Cd²+ and 0.521 M in Ag+. (a) What concentration of C₂04² is necessary to begin precipitation? (Neglect volume changes.) [C₂04²] = M. (b) Which cation precipitates first? O Cd²+ O Ag+ [C₂04²-] = The Ksp of CdC₂04 is 1.42e-08. The Ksp of Ag₂C₂O4 is 5.4-12. (c) What is the concentration of C₂04² when the second cation begins to precipitate? M.
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