A solution was prepared by dissolving about 30.00m g of EDTA in approximately 1 L of water and standardizing against 50.00-mL aliquots of 0.004356 M Mg2+. An average titration of 32.65 mL was required. Calculate the molar concentration of the EDTA.
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- An antacid tablet, weighing 1.25 g, was dissolved in a 1.0 L volumetric flask to allow for determination of calcium carbonate and magnesium carbonate contents. After preparing the solution, an aliquot of 10.0 ml was transferred to an Erlenmeyer flask containing a buffer solution with pH = 10. This aliquot was then titrated with EDTA 0.0040 mol/L and the average volume spent was 15.01 mL. To measure calcium after precipitation After the magnesium was fractionated, a second 10.00 mL aliquot of the stock solution was transferred to an Erlenmeyer flask. and the pH of the present solution was adjusted to a value of approximately 13. In EDTA titration, the volume consumed for observation of the end point was equal to 13.03 mL. Based on this information, (a) Outline the two steps involved, representing the related reactions. (b) Calculate the concentrations of CaCO3 and MgCO3 present in the initial solution. (c) Calculate the masses of CaCO3 and MgCO3 present in the pellet. (d) Calculate the…. An antacid tablet, weighing 1.25 g, was dissolved in a 1.0 L volumetric flask to allow for determination of calcium carbonate and magnesium carbonate contents. After preparing the solution, an aliquot of 10.0 ml was transferred to an Erlenmeyer flask containing a buffer solution with pH = 10. This aliquot was then titrated with EDTA 0.0040 mol/L and the average volume spent was 15.01 mL. To measure calcium after precipitation. After the magnesium was fractionated, a second 10.00 mL aliquot of the stock solution was transferred to an Erlenmeyer flask, and the pH of the present solution was adjusted to a value of approximately 13. In EDTA titration, the volume consumed for observation of the end point was equal to 13.03 mL. Based on this information, a) Outline the two steps involved, representing the related reactions./5 b) Calculate the concentrations of CaCO3 and MgCO3 present in the initial solution./6 c) Calculate the masses of CaCO3 and MgCO3 present in the pellet./6 d) Calculate…Titration of 25.0 mL of a 0.0500 M Zn2+ solution with 0.0550 M EDTA in a solution buffered at pH 8. Assume that the temperature is 25 oC and that the formation constant for Zn2+ is 3.13 x 1016 at this temperature. What is the pZn of the solution after 30 mL of titrant have been added?
- Calamine, which is used for relief of skin irritations, is a mixture of zinc and iron oxides. A 1.022-g sample of dried calamine was dissolved in acid and diluted to 250.0 mL. A 50.00 mL aliquot was suitably buffered and titrated with 2.40 mL of 0.002727 M ZnY-2 (Zn-EDTA) solution to allow the following reaction: Fe+3 + ZnY-2 → FeY- + Zn+2. Molecular mass: Fe2O3 = 165.74 a. The weight of sample in the aliquot portion is _________g ? b. the percentage composition of Fe2O3 in the sample is ______ % ?A 0.5745 g sample of an alloy containing principally bismuth and lead is dissolved in nitric acid and diluted to 250.0 mL in a volumetric flask. A 50.00 mL aliquot is withdrawn, the pH adjusted to 1.5, and the bismuth titrated with 30.26 mL of 0.01024 M EDTA. The pH of the solution is then increased to 5.0 and the lead titrated with 20.42 mL of the same EDTA solution. Calculate the percentages of lead and bismuth in the alloy.3. An antacid tablet, weighing 1.25 g, was dissolved in a 1.0 L volumetric flask to allow for determination of calcium carbonate and magnesium carbonate contents. After preparing the solution, an aliquot of 10.0 ml was transferred to an Erlenmeyer flask containing a buffer solution with pH = 10. This aliquot was then titrated with EDTA 0.0040 mol/L and the average volume spent was 15.01 mL. To measure calcium after precipitation. After the magnesium was fractionated, a second 10.00 mL aliquot of the stock solution was transferred to an Erlenmeyer flask, and the pH of the present solution was adjusted to a value of approximately 13. In EDTA titration, the volume consumed for observation ofthe end point was equal to 13.03 mL. Based on this information,a) Outline the two steps involved, representing the related reactions./5b) Calculate the concentrations of CaCO3 and MgCO3 present in the initialsolution./6c) Calculate the masses of CaCO3 and MgCO3 present in the pellet./6d) Calculate the…
- A chemist is given a piece of limestone and told that 50.00% of the sample exists as calcium oxide (CaO). To analyze the sample, the chemist wants to dissolve a portion of the sample in 100 mL and then titrate an aliquot (10 mL) using 0.005300 M EDTA. How much sample (in grams) is needed if a titration volume of 25.00 mL EDTA is desired?As part of a geological team that studied a local cave, you brought with you a bunch of 1.00 g rock samples to be studied. Each rock was prepared and titrated against 0.050 M EDTA. a. Calculate the percent calcite (CaCO3) content of rock A if it was titrated with 48.0 mL EDTAAs part of a geological team that studied a local cave, you brought with you a bunch of 1.00 g rock samples to be studied. Each rock was prepared and titrated against 0.050 M EDTA.a. Calculate the percent calcite (CaCO3) content of rock A if it was titrated with 48.0 mL EDTAb. Calculate the percent brucite (Mg(OH)2) content of rock B if it was titrated with 76.5 mL EDTA
- An EDTA solution was prepared by dissolving approximately 3 grams of Na2H2Y•H2O in sufficient water to give 1 liter of solution. This solution was then standardized against 50.00 mL aliquots of 0.004517 molar Mg2+. An average titration volume of 32.22 mL was required. Determine the molar concentration of EDTA.7. A solution contains 1.569 mg/mL of CoSO4(MM = 155.0 g/mol). Calculate the volume of 0.007840 M EDTA needed to titrate a 25.00 mL aliquot of this solution. 8. Calculate the volume of 0.0500 M EDTA needed to titrate 29.13 mL of 0.0598 M Mg(NO3)2.Given that the titration of Ca2+ and Mg2+ in a 50.00-mL sample of hard water required 22.35 mL of 0.01115 M EDTA. A second 50.00-mL aliquot was made strongly basic with NaOH to precipitate the Mg2+ as Mg(OH)2(s) . The supernatant liquid was titrated with 15.19 mL of the EDTA solution. Calculate the concentration in ppm of CaCO3 in the sample.
