A thermodynamic process occurs with a heat lost by the system. Does the entropy of the system necessarily decrease? Why or why not? a. Yes. b. No, because there are other mechanisms to change the entropy. c. No, because the Second Law of Thermodynamics forbids the decrease in entropy of a system. d. No, because heat lost means increase in the entropy. e. No, because transfer of heat is not related to the entropy change at all.

A thermodynamic process occurs with a heat lost by the system. Does the entropy of the system necessarily decrease? Why or why not? a. Yes. b. No, because there are other mechanisms to change the entropy. c. No, because the Second Law of Thermodynamics forbids the decrease in entropy of a system. d. No, because heat lost means increase in the entropy. e. No, because transfer of heat is not related to the entropy change at all.

College Physics

1st Edition

ISBN:9781938168000

Author:Paul Peter Urone, Roger Hinrichs

Publisher:Paul Peter Urone, Roger Hinrichs

Chapter15: Thermodynamics

Section: Chapter Questions

Problem 31CQ: Explain how water’s entropy can decrease when it freezes without violating the second law of...

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(a) On a winter day, a certain house loses 5.00108J of heat to the outside (about 500,000 Btu). What is the total change in entropy due to this heat transfer alone, assuming an average indoor temperature of 21.0C and an average outdoor temperature of 5.00C ? (b) This large change in entropy implies a large amount of energy has become unavailable to do work. Where do we find more energy when such energy is lost to us?
(a) How much heat transfer occurs from 20.0 kg of 90.0C water placed in contact with 20.0 kg of 10.0C water, producing a final temperature of 50.0C ? (b) How much work could a Carnot engine do with this heat transfer, assuming it operates between two reservoirs at constant temperatures of 90.0C and 10.0C ? (c) What increase in entropy is produced by mixing 20.0 kg of 90.0C water with 20.0 kg of 10.0C water? (d) Calculate the amount of work made unavailable by this mixing using a low temperature of 10.0C, and compare it with the work done by the Garnet engine. Explicitly show how you follow the steps in the Problem-Solving Strategies for Entropy. (e) Discuss how everyday processes make increasingly more energy unavailable to do work, as implied by this problem.
(a) In reaching equilibrium, how much heat transfer occurs from 1.00 kg of water at 40.0C when it is placed in contact with 1.00 kg of 20.0C water in reaching equilibrium? (b) What is the change in entropy due to this heat transfer? (c) How much work is made unavailable, taking the lowest temperature to be 20.0C ? Explicitly show how you follow the steps in the Problem-Solving Strategies for Entropy.
A large electrical power station generates 1000 MW of electricity with an efficiency of 35.0%. (a) Calculate the heat transfer to the power station, Qh, in one day. (b) How much heat transfer Qc occurs to the environment in one day? (c) If the heat transfer in the cooling towers is from 35.0C water into the local air mass, which increases in temperature from 18.0C to 20.0C, what is the total increase in entropy due to this heat transfer? (d) How much energy becomes unavailable to do work because of this increase in entropy, assuming an 18.0C lowest temperature? (Part of Qccould be utilized to operate heat engines or far simply heating the surroundings, but it rarely is.)
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Explain why a building made of bricks has smaller entropy than the same bricks in a disorganized pile. Do this by considering the number of ways that each could be formed (the number of microstates in each macrostate).
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