a. Does this graph establish the order of the reaction? b. If it does, what is the rate law in respect to [reactant] and what is k for this reaction?

Fundamentals Of Analytical Chemistry
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Chapter32: Gas Chromatography
Section: Chapter Questions
Problem 32.15QAP
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a. Does this graph establish the order of the reaction? b. If it does, what is the rate law in respect to [reactant] and what is k for this reaction?
G.
Mixture
Con [H,SO,]
Time
0.001
66
2.
0.002
26
3
0.003
17
4
0.004
10
Initial Concentration of [B] vs. Time
• Con [H2S03]
y =-5E-05x +0.0039
R =0.8329
0.0045
0.004
0.0035
0.003
0.0025
0.002
0.0015
0.001
0.0005
10
20
30
40
50
60
70
Time (s)
4.
Concentration of (H,SO3]
Transcribed Image Text:G. Mixture Con [H,SO,] Time 0.001 66 2. 0.002 26 3 0.003 17 4 0.004 10 Initial Concentration of [B] vs. Time • Con [H2S03] y =-5E-05x +0.0039 R =0.8329 0.0045 0.004 0.0035 0.003 0.0025 0.002 0.0015 0.001 0.0005 10 20 30 40 50 60 70 Time (s) 4. Concentration of (H,SO3]
Expert Solution
Data given:

Graph for plot of concentration of H2SO3 verses time is a straight line plot with a negative slope. 

Mixture Conc. [H2SO3] /M Time (s)
1 0.004 10
2 0.003 17
3 0.002 26
4 0.001 66

 The data in the table has been rearranged....

From table it can be concluded that, as time increases the concentration of H2SO3 decreases, but the decrease is infinitely less compared to the increases in time. 

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