A. Estimate the specific volume of water at temperatures T; = 300°C and T, 600°C for the following pressures: p, = 400 kPa and p, = 40 bar using : (a) Van de Waals constitutive eq. (b) Redlich Kwong constitutive eq. (c) Lee and Kesler correlation for compressibility factor (d) Ideal gas eq. (el Thermodynamic tables. %3D %3D

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Solve part A & E

A. Estimate the specific volume of water at temperatures T, = 300°C and T, =
600°C for the following pressures: p, = 400 kPa and p, = 40 bar using :
(a) Van de Waals constitutive eq.
(b) Redlich Kwong constitutive eq.
(c) Lee and Kesler correlation for compressibility factor
(d) Ideal gas eq.
(e) Thermodynamic tables.
%3D
%3D
%3D
Transcribed Image Text:A. Estimate the specific volume of water at temperatures T, = 300°C and T, = 600°C for the following pressures: p, = 400 kPa and p, = 40 bar using : (a) Van de Waals constitutive eq. (b) Redlich Kwong constitutive eq. (c) Lee and Kesler correlation for compressibility factor (d) Ideal gas eq. (e) Thermodynamic tables. %3D %3D %3D
Expert Solution
Step 1

The deviation of real substance from ideal properties is given by cubic equation of state. There are different cubic state equations like Vander Waal, Redlich etc. There will be two new constants which provide the difference between real gas and ideal gas. The two constants represent intermolecular forces and volume of gas particles.

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