a. m-chloroethylbenzene I.CH.CCI AICI, ZaHg) H,NNH, or HCL, A HO, A CH CH,CH, CH, 2 HO or H Pd/C CI CI b. m-hydroxybenzoic acid СООН CH, COOH CH CI H,CrO HNO AICH H SO, NO H, Pd/C COOH СООН HOO) Cu O ON N HCI Cu(NO H-O or H,O.A O°C OH NH

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter20: Carboxylic Acids And Nitriles
Section20.3: Biological Acids And The Henderson–hasselbalch Equation
Problem 5P: Calculate the percentages of dissociated and undissociated forms present in the following solutions:...
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Show the mechanism for both reactions of a and b. 

a. m-chloroethylbenzene
LCH.CCI
AICI,
ZaHg)
or
HCL, A
HO, A
CH
H,NNH,
CH,CH,
CH,
2 HO
or H, Pd/C
CI
CI
b. m-hydroxybenzoic acid
СООН
CH,
COOH
CH CI
H.CrO
HNO
AICH
H-SO,
NO
H, Pd/C
СООН
HOO)
Cu O
СООН
Cu(NO
H-O
ON N
HCI
O°C
or
OH
H,O.A
NH
Transcribed Image Text:a. m-chloroethylbenzene LCH.CCI AICI, ZaHg) or HCL, A HO, A CH H,NNH, CH,CH, CH, 2 HO or H, Pd/C CI CI b. m-hydroxybenzoic acid СООН CH, COOH CH CI H.CrO HNO AICH H-SO, NO H, Pd/C СООН HOO) Cu O СООН Cu(NO H-O ON N HCI O°C or OH H,O.A NH
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