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A. Shown below are the Fischer projections of four isomeric phosphorylated tetroaldoses. One of these is compound DAVID, an intermediate of the Calvin cycle which is an important metabolic pathway in plants involving the assimilation of carbon dioxide from the atmosphere. H. H. H. H- OH но H. HO но H. H- HO HO - H- HO- ČH2OPO,2- CH,OPO, ČH,OPO,2 CH,OPO,2 K Y R 1. If DAVID has R configuration at both chirality centers, which of the given structures is it? 2. Which of the following compounds is expected to have the same melting and boiling points as DAVID?

A. Shown below are the Fischer projections of four isomeric phosphorylated tetroaldoses. One of these is compound DAVID, an intermediate of the Calvin cycle which is an important metabolic pathway in plants involving the assimilation of carbon dioxide from the atmosphere. H. H. H. H- OH но H. HO но H. H- HO HO - H- HO- ČH2OPO,2- CH,OPO, ČH,OPO,2 CH,OPO,2 K Y R 1. If DAVID has R configuration at both chirality centers, which of the given structures is it? 2. Which of the following compounds is expected to have the same melting and boiling points as DAVID?

Organic Chemistry
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter16: Aldehydes And Ketones
Section: Chapter Questions
Problem 16.67P: Treatment of -D-glucose with methanol in the presence of an acid catalyst converts it into a mixture...
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III . A 1-2
A. Shown below are the Fischer projections of four isomeric phosphorylated tetroaldoses. One of these is compound DAVID, an intermediate of the Calvin cycle which is an important metabolic pathway in plants involving the assimilation of carbon dioxide from the atmosphere. H. H. H. O' H- OH но H. HO- но H. H- Но H. HO H- H- HO- ČH2OPO,2- CH2OPO, ČH,OPO,2 ČH,OPO,2- K Y R 1. 1. If DAVID has R configuration at both chirality centers, which of the given structures is it? 2. Which of the following compounds is expected to have the same melting and boiling points as DAVID?
Transcribed Image Text:A. Shown below are the Fischer projections of four isomeric phosphorylated tetroaldoses. One of these is compound DAVID, an intermediate of the Calvin cycle which is an important metabolic pathway in plants involving the assimilation of carbon dioxide from the atmosphere. H. H. H. O' H- OH но H. HO- но H. H- Но H. HO H- H- HO- ČH2OPO,2- CH2OPO, ČH,OPO,2 ČH,OPO,2- K Y R 1. 1. If DAVID has R configuration at both chirality centers, which of the given structures is it? 2. Which of the following compounds is expected to have the same melting and boiling points as DAVID?
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