Automobiles require coolant liquid to cool down combustion chambers in the engine. The followingreaction occurs when gasoline is burned in combustion chambers in automobiles.N2(9) + O29) = 2NO)K = 5 x 10 31 at 25°C,K = 0.0013 at 2100°C1. Apply the above chemical equilibrium equation to write an equilibrium constant expression. [A, 1]2. Apply your understanding of equilibrium constants to explain why adding a coolant to cool downthe engine and the combustion chamber where this reaction occurs is beneficial to theenvironment. Compare the magnitude of the K value at each temperature and its meaning. [A, 2]

The equilibrium constant is the ration between the products of molar concentration of the products…

Automobiles require coolant liquid to cool down combustion chambers in the engine. The following reaction occurs when gasoline is burned in combustion chambers in automobiles. K = 5 x 10 31 at 25°C, N2(2) + O2() = 2NO9) K = 0.0013 at 2100°C 1. Apply the above chemical equilibrium equation to write an equilibrium constant expression. [A,

Automobiles require coolant liquid to cool down combustion chambers in the engine. The following reaction occurs when gasoline is burned in combustion chambers in automobiles. K = 5 x 10 31 at 25°C, N2(2) + O2() = 2NO9) K = 0.0013 at 2100°C 1. Apply the above chemical equilibrium equation to write an equilibrium constant expression. [A,

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter12: Chemical Equilibrium

Section: Chapter Questions

Problem 2RQ: What is the law of mass action? Is it true that the value of K depends on the amounts of reactants...

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Because calcium carbonate is a sink for CO32- in a lake, the student in Exercise 12.39 decides to go a step further and examine the equilibrium between carbonate ion and CaCOj. The reaction is Ca2+(aq) + COj2_(aq) ** CaCO,(s) The equilibrium constant for this reaction is 2.1 X 10*. If the initial calcium ion concentration is 0.02 AI and the carbonate concentration is 0.03 AI, what are the equilibrium concentrations of the ions? A student is simulating the carbonic acid—hydrogen carbonate equilibrium in a lake: H2COj(aq) H+(aq) + HCO}‘(aq) K = 4.4 X 10"7 She starts with 0.1000 AI carbonic acid. What are the concentrations of all species at equilibrium?
What is the law of mass action? Is it true that the value of K depends on the amounts of reactants and products mixed together initially? Explain. Is it true that reactions with large equilibrium constant values are very fast? Explain. There is only one value of the equilibrium constant for a particular system at a particular temperature, but there is an infinite number of equilibrium positions. Explain.
At room temperature, the equilibrium constant Kc for the reaction 2 NO(g) ⇌ N2(g) + O2(g) is 1.4 × 1030. Is this reaction product-favored or reactant-favored? Explain your answer. In the atmosphere at room temperature the concentration of N2 is 0.33 mol/L, and the concentration of O2 is about 25% of that value. Calculate the equilibrium concentration of NO in the atmosphere produced by the reaction of N2 and O2. How does this affect your answer to Question 11?
Consider 0.200 mol phosphorus pentachloride sealed in a 2.0-L container at 620 K. The equilibrium constant, Kc, is 0.60 for PCl5(g) PCl3(g) + Cl2(g) Calculate the concentrations of all species after equilibrium has been reached.
Hydrogen and carbon dioxide react at a high temperature to give water and carbon monoxide. H2(g) + CO2(g) H2O(g) + CO(g) (a) Laboratory measurements at 986 C show that there are 0.11 mol each of CO and H2O vapor and 0.087 mol each of H2 and CO2 at equilibrium in a 50.0-L container. Calculate the equilibrium constant for the reaction at 986 C. (b) Suppose 0.010 mol each of H2 and CO2 are placed in a 200.0-L container. When equilibrium is achieved at 986 C, what amounts of CO(g) and H2O(g), in moles, would be present? [Use the value of Kc from part (a).]
The value of the equilibrium constant, K, is dependent on which of the following? (There may be more than one answer.) a. the initial concentrations of the reactants b. the initial concentrations of the products c. the temperature of the system d. the nature of the reactants and products Explain.
Explain that equilibrium is dynamic, and that at equilibrium the forward and backward reaction rates are equal.
Methanol, a common laboratory solvent, poses a threat of blindness or death if consumed in sufficient amounts. Once in the body, the substance is oxidized to produce formaldehyde (embalming fluid) and eventually formic acid. Both of these substances are also toxic in varying levels. The equilibrium between methanol and formaldehyde can be described as follows: CH3OH(aq)H2CO(aq)+H2(aq) Assuming the value of K for this reaction is 3.7 1010, what are the equilibrium concentrations of each species if you start with a 1.24 M solution of methanol? What will happen to the concentration of methanol as the formaldehyde is further converted to formic acid?