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- What is the purpose of the hexane in the halogen displacement? Intowhich layer (water or hexane) would the following species reside?Cl‐, I2, Cl2, Br‐, I‐, Br2Children’s toys and jewelry were assessed for their contamination by potentially toxic elements (PTE). This includes traces of As (74.92 g/mol), Cd (112.4 g/mol), Pb (207.2 g/mol), and Zn (65.39 g/mol) among others. The concentrations of these PTEs were determined to characterize the subsequent health risks, and to possibly reinforce better legislation on the manufacturing of these products. If 365 ppb of Zn was observed, what is its equivalent in %(w/w)? A sample of plastic toy was treated resulting to a 500 mL solution. What is the concentration of Pb in ppm if 25 μg of Pb is found in the sample? A 250 mL stock solution of 1.5 M As standard was prepared. What volume (in mL) of As stock solution must you use to prepare 50 mL of 0.75 M As solution? If the treatment used HNO3 (ρ = 1.51 g/mL) as the solvent during dissolution, and the density of Cd is 8.7 g/mL, what is the concentration of Cd in molality if the amount of Cd found in a 250 mL solution was 24 mg?Refer to the following equation: Mg (s) + 2HNO3(aq) -> Mg(NO3)2 (aq) + H2 (g) A reaction between 0.359 grams of Mg and 21.12mL of a 0.450M HNO3 solution was conducted in a room witht he following conditions: 27.5 degrees Celius, 723mmHg of atospheric pressure. If .15mL of H2 were collected over water (by the water displacement method), calculate the percent yeild of the reaction. (Pressure H2O at 27.5 degrees Celius = 27.82 mmHg)
- One of the chemical controversies of the nineteenth century concerned the element beryllium (Be). Berzelius originally claimed that beryllium was a trivalent element (forming Be3+ ions) and that it gave an oxide with the formula Be2O3. This resulted in a calculated atomic mass of 13.5 for beryllium. In formulating his periodic table, Mendeleev proposed that beryllium was divalent (forming Be2+ ions) and that it gave an oxide with the formula Be2O3. This assumption gives an atomic mass of 9.0. In 1894, A. Combes (Comptes Rendus 1894, p. 1221) reacted beryllium with the anion C5H7O2and measured the density of the gaseous product. Combess data for two different experiments are as follows: I II Mass 0.2022 g 0.2224 g Volume 22.6 cm3 26.0 cm3 Temperature 13C 17C Pressure 765.2 mm Hg 764.6 mm If beryllium is a divalent metal, the molecular formula of the product will be Be(C5H7O2)2; if it is trivalent, the formula will be Be(C5H7O2)3. Show how Combess data help to confirm that beryllium is a divalent metal.The thermal decomposition of potassium chlorate can be used to produce oxygen. 2KClO3 --> 2KCl +3O2 What volume of O2 gas at 298 K and 1.0 atm pressure is produced by the decomposition of 7.50 g of KClO3 (FW=122.6)?During the discussion of gaseous diffusion for enriching uranium, it was claimed that 235UF6 diffuses 0.4% faster than 238UF6. Show the calculation that supports this value. The molar mass of 235UF6 = 235.043930 + 6 x 18.998403 = 349.034348 g/mol, and the molar mass of 238UF6 = 238.050788 + 6 x 18.998403 = 352.041206 g/mol.
- Oxyacetylene torches rely on a precise mixture of fuel (C2H2(g)) to oxygen to optimize the welding process. _ C2H2 (g) + _ O2 (g) ---> CO2 (g) + _H2O (g) Calculate the volume (in L) of O2(g) required to react completely with 14.5 L of acetylene. Assume both substances are at SATP.A sample of potassium permaganate (KMnO4) reacts to completion with sodium oxalate (Na2C2O4) in the folowing redox reaction: 2MnO4- (aq) + 5C2O4-2 (aq) + 16H+ (aq) --> 10CO2 g) + 2Mn+2 (aq) + 8H2O (l) The volume of carbon dixoide released by the reaction at 297 K and 1.00 atm was 138 L. How many moles of potassium permanganate reacted? The Universal Gas Constant is 0.082057 L x atm/ mol x K. (answer in sig figs)A N2 molecule at 20 ⁰C is released at sea level to travel upward. Assuming that the molecule does not collide with other molecules, how far will it travel before coming to rest? Do the same calculation for a He atom. Hint: to calculate the height h, the molecule will travel, equate its kinetic energy with the potential energy it attains at h, which is mgh. Here m is the mass, and g is the gravitational acceleration
- 1. A student following the procedure described in this module collected the following data: mass Mg, g 0.0243 initial syringe volume, mL 1.0 final syringe volume, mL 26.5 barometric pressure, torr 754 temperature, K 298 Determination#1 The value of the gas law constant (R) is 0.0822 L.atm/mol.K Determination #2 he volume of hydrogen gas produced by the reaction of 0.243 g of magnesium metal and collected at 750 torr and 298 K = 248 mL The results of this experiment are greatly affected by the care with which each of the steps is completed (a) Describe the error that would occur if the magnesium were to slide into the HCl in the test tub before the system is sealed off (b) What would be the effect on the results of a rise in the room temperature from 22.0 celcius, when determination #1 was done, to 25.3 celcius, when determination #2 was made? (c) Why must the surface coating of MgO be removed prior to determining the mass of magnesium used in the experiment? (d) What would be the…Soil vapor extraction (SVE) is used to remove volatile or-ganic pollutants, such as chlorinated solvents, from soil at haz-ardous waste sites. Vent wells are drilled, and a vacuum pump is applied to the subsurface. (a) How does this remove pollutants?(b) Why does heating combined with SVE speed the process?1. A student following the procedure described in this module collected the following data: mass Mg, g 0.0243 initial syringe volume, mL 1.0 final syringe volume, mL 26.5 barometric pressure, torr 754 temperature, K 298 (a) calculate the gas law constant (b) What would be the volume of hydrogen gas produced by the reaction of 0.243 g of magnesium metal and collected at 750 torr and 298 K? Use the value for R found in part 1.