Calculate potentials after the addition of 10.00, 25.00, 50.00, and 50.10 mL of the reagent. Where necessary, assume that [H+] = 1.00 throughout A.) 50.00 mL of 0.1000 M Fe(CN)6 4- with 0.05000 M Tl3+

Calculate potentials after the addition of 10.00, 25.00, 50.00, and 50.10 mL of the reagent. Where necessary, assume that [H+] = 1.00 throughout A.) 50.00 mL of 0.1000 M Fe(CN)6 4- with 0.05000 M Tl3+

Principles of Instrumental Analysis

7th Edition

ISBN:9781305577213

Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Chapter23: Potentiometry

Section: Chapter Questions

Problem 23.14QAP

See similar textbooks

Related questions

Q: C. Draw the chemical structure for each of the following: Ex. 2,3-dimethylpentane CH3 CH3 CH-CH-CH-C...

Q: What type of precipitate is BaSO4?

A: Answer of the question given below,

Q: What is the concentration of a solution of Ca(OH)2 for which the pH is 11.68?

A: Hydrogen ion concentration is an important parameter of an aqueous solution. The concentration of th...

Q: Organic product Inorganic product Br H.

Q: What is the volume of Hydrogen gas that was produced at the action of dilute sulfuric acid to 32.7g ...

A: Given, H2SO4 + Zn ➝ ZnSO4 + H2 Mass of Zinc (Zn) react = 32.7 g Volume of hydrogen (H2) gas produced...

Q: Two students determine the percentage of lead in a sample as a laboratory exercise. The true percent...

Q: 10-mL aliquot of the previously prepared NaCl solution into a 100-mL volumetric flask. What is the ...

A: Given, Initial Molarity(M1) = 0.68 M Initial Volume (V1) = 10 mL Final Volume (V2) = 100 mL Final Mo...

Q: Identify the electron pair geometry of carbonyl chloride (COCl2)

Q: Balance the following Redox reactions using number method 1. HNO, + H3ASO H3 AsO4+ H2

Q: the pressure in th

Q: In the following reaction, a primary alcohol is fully oxidized to a carboxylic acid. Draw the aldehy...

Q: Silanone (SİH2O) and silanol (SİH3OH) are species believed to be important,in the oxidation of silan...

Q: Assign E or Z geometry in the following compound. Explain how you arrived at your answers and clear ...

A: If the two groups (attached to each carbon of double bond) of high priority are on the same side of ...

Q: 5.Based on your research, which of these metals you think would be the "greenest" metal to use? Just...

A: Answer - According to the question - The greenest metal is Aluminium (Al) because it is a very envir...

Q: What is the K, reaction of HCN? K, reaction: The K, of HCN is 6.2 x 10-10. What is the K, value for ...

Q: 6. Provide the COSY spectrum and me-HSQC spectrum of 2-pentanone. Comment on the difference between ...

A: This Question is based upon 2-D NMR

Q: Draw the compound that would produce 4-ethyl-3-hexanol in the presence of a nickel catalyst and hydr...

A: Given-> Product is - 4-ethyl-3-hexanol

Q: Calculate the energy levels of the 7-network in octatetraene, C3H10 (CC-C=C-C=C-C=C), using the part...

A: Given : C=C bond = 135 pm C - C bond = 154 pm

Q: Does a reaction occur when aqueous solutions of ammonium acetate and aluminum sulfate are combined? ...

A: Let's write the molecular reaction equation between ammonium acetate and aluminum sulfate.

Q: Weight of NaCl- 0.4016g dissolved in 10mL distilled water. FInd the molarity of NaCl

A: Molarity of a solution is the no of moles of solute dissolved in per litre of solution the funding t...

Q: 1. Determine the volume of occupied by 0.0123 pounds of carbon dioxide gas at STP. I kg = 2.2 pounds

A: 1) given, Mass of carbon dioxide (CO2) gas = 0.0123 pound = 0.00559 kg = 5.59 g Converting pound in...

Q: 1.Can you name the conjugate acid of each? 2. Explain what happened with the picture.

Q: Propose a synthesis of the following imine from the given alkene. Provide the products of each step....

A: The alkene can be first converted to haloalkane via Anti Markonikov addition and then via kornblum o...

Q: IV. Challenge Problem Part I. Building a Synthesis Toolbox Fill in the missing reagents over each ar...

Q: The theoretical yield of an experiment is 8.76 g of product. The experimental yield is 6.45 g. What ...

A: Percentage yield = Experimental yield divide by theoretical yield × 100

Q: 4. At temperature 500 °C, what is the volume of occupied 4.2 grams carbon dioxide gas at STP?

A: Number of moles is calculated by dividing given mass with molecular mass.

Q: Find the Normality of NaOH and Normality of HCl from the following data: Weight of KHP Final Reading...

A: KHP is used to standardize NaOH. Both react in 1:1 ratio.

Q: There are solutions of Ba(NO3)2 and A12(SO4)3 with the same molar concentration. Which of the soluti...

Q: Experiment 2 given: rate = k[H;O2]'[I]'[H'J° Sol'n # Water (mL) 0.050 M 0.1 % 0.050 M 0.050 1.033M T...

Q: 2 steps N3 HO.

Q: Calculate the number of hydronium ions in 42.40 mL of an aqueous solution with a pH of 6.82. number ...

Q: CH;OH НО OH What is the name of this structure? OH OH alpha-D-gulopryranose beta-L-gulofuransone alp...

Q: The reaction: C2H5Cl(g)---->C2H4(g)+HCl(g) is the first order in C2H5Cl.The rate constant is 1.60 x ...

A: First-order reaction: The rate of the first-order reaction depends only on one reactant.

Q: Question 32 Which of the following compounds is a strong electrolyte? O N2OH O H,0 O CH;OH O CH3CH2O...

A: Strong electrolyte is electrolyte which can dissociate into ions .

Q: Calculate potentials after the addition of 10.00, 25.00, 50.00, and 50.10 mL of the reagent. Where ...

Q: In which solution will Lead sulfate (PbSO4) be most soluble? 0.5 M PB (NO3)2 0.5 M NaNO3 0.5 M Na2S...

A: KSP of PbSO4 = 1.6 * 10-8 PbSO4 (s) ⇔ Pb2+ (aq) + SO42- (aq) ...

Q: Complete the autoionization reaction for water. autoionization of water: H,0 + H,0 =

Q: Give the name of the given compound and clear parent chain in clear ha

Q: [H30*] = %3D

Q: 15. What is the molarity of an aqueous NH solution that has a pH of 11.17? Kb= 1.8 x 10-5.

Q: . Calculate the mass of hydrogen bromide once bromine combines with 24.3 L of hydrogen. a) Write and...

A: When hydrogen reacts with bromine ,it gives hydrogen bromide. At STP volume of 1 mol of gas is 22.4 ...

Q: C. H. シート CH3CH2CH2

A: When butyraldehyde is treated with H2 in the presence of Pd catalyst then the product formed is buta...

Q: Performed on samples in the range of 0.01 to 0.1 g. O Macro analysis O Semimicro analysis O Micro an...

A: Based on the size of analyse they can be classified as

Q: Propanol is used as a solvent in the pharmaceutical industry, mainly for resins and cellulose esters...

Q: Predict the product for the following reaction. CH;CH,NH2 OH NHCH2CH3 `NHCH2CH3 NCH2CH3 II II ОН NCH...

Q: 22-88. Calculate the equilibrium chloride ion con- centration in a solution made by mixing 50.0 mL o...

A: Given the volume of 1.00 M sodium chloride, NaCl = 50.0 mL Volume of 1.00 M mercury(I) nitrate, Hg2...

Q: . A radioactive parent isotope with 600 atoms. After the decay, 450 daughter atoms were produced. Ca...

Q: Try to create a WORD PROBLEM about Hess's Law. Make sure to include your solution.

Q: The reaction of hydrogen gas and nitrogen gas to form ammonia is a well-known process that is an imp...

Q: What is the mean speed, K, of N2 molecules in air at 25°C?

A: Answer of the question given below,

Question

Calculate potentials after the addition of 10.00, 25.00,

50.00, and 50.10 mL of the reagent. Where necessary,

assume that [H+] = 1.00 throughout

A.) 50.00 mL of 0.1000 M Fe(CN)6

4- with 0.05000 M Tl3+

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

Step 2

Step 3

Step 4

Step 5

Step 6

Step by step

Solved in 6 steps with 5 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Calculate potentials after the addition of 10.00, 25.00, 50.00, and 50.10 mL of the reagent. Where necessary, assume that [H+ ] = 1.00 throughout. (b) 50.00 mL of 0.1000 M Fe(CN)6 4- with 0.05000 M Tl3+ .
Calculate potentials after the addition of 10.00, 25.00, 50.00, and 50.10 mL of the reagent. Where necessary,Assume that [H+] = 1.00 throughout 50.00 mL of 0.05000 M U4+ with 0.02000 M MnO4
Calculate potentials after the addition of 10.00, 25.00,50.00, and 50.10 mL of the reagent. Where necessary,assume that [H+] = 1.00 throughout.(a) 50.00 mL of 0.1000 M V2+ with 0.05000 M Sn4+.(b) 50.00 mL of 0.1000 M Fe(CN)64- with 0.05000 M Tl3+.(c) 50.00 mL of 0.05000 M U4+ with 0.02000 M MnO4
A 40.00-mL aliquot of 0.05000 M HNO2 is diluted to 75.00 mL and titrated with 0.0800 M Ce4+ . The pH of the solution is maintained at 1.00 throughout the titration; the formal potential of the cerium system is 1.44 V. Calculate the potential of the indicator electrode with respect to a saturated calomel reference electrode after the addition of 5.00 mL of cerium (IV). (Use a MW value in 4 decimal places)
50.00 ml of 0.1000 M Fe(CN)64- solution is titrated with 0.05000 M Tl3+ solution potentiometrically using S.C.E. and Pt electrodes. Calculate the values of the potential when 10.0, 50.0 and 60.0 ml of titrant have been added.
Consider the titration of 25.0 mL of 0.010 0 M Sn21 by 0.050 0 M Tl31 in 1 M HCl, using Pt and saturated calomel electrodes. (a) Write a balanced titration reaction. (b) Write two half-reactions for the indicator electrode. (c) Write two Nernst equations for the cell voltage. (d) Calculate E at the following volumes of Tl31: 1.00, 2.50, 4.90, 5.00, 5.10, and 10.0 mL. Sketch the titration curve.
Consider the titration of 100.0 mL of 0.010 0 M Ce4+ in 1 M HClO4 with 0.040 0 M Cu+ to give Ce3+ and Cu2+. Calculate the potential of the indicator electrode after adding 24.5 mL of Cu+.
A 40.00-mL aliquot of 0.05000 M HNO2 is diluted to 75.00 mL and titrated with 0.0800 M Ce4+. The pH of the solution is maintained at 1.00 throughout the titration; the formal potential of the cerium system is 1.44V a. Calculate the potential of the indicator electrode with respect to a saturated calomel reference electrode after the addition of 5.00, 10.00, 15.00, 25.00, 40.00, 49.00, 49.50, 49.60, 49.70, 49.80, 49.90, 49.95, 49.99, 50.00, 50.01, 50.05, 50.10, 50.20, 50.30, 50.40, 50.50, 51.00, 60.00, 75.00 and 90.00 mL of Cerium (IV). b. Draw a titration curve for these data. c. Generate a first- and second-derivative curve for these data. Does the volume at which the second-derivative curve crosses zero correspond to the theoretical equivalence point? Why or why not?
Consider the titration of 25.0mL 0.0100M Sn2+by 0.0500M Tl3+in 1M HCl, using Pt and saturated calomel electrodes. 1)Calculate E at the following volumes of Tl3+: 1, 2.5, 4.9, 5, 5.1, and 10 mL
Consider the titration of 25.0ml 0.0100M Sn2+ by 0.0500M Tl3+ in 1M HCl using Pt and saturated calomel electrodes , calculate E at following volumes of Tl3+ : 1, 5 and 10ml
Consider the titration of 25.0 mL of 0.050 0 M Sn21 with 0.100 M Fe31 in 1 M HCl to give Fe21 and Sn41, using Pt and saturated calomel electrodes. (a) Write a balanced titration reaction. (b) Write two half-reactions for the indicator electrode. (c) Write two Nernst equations for the cell voltage. (d) Calculate E at the following volumes of Fe31: 1.0, 12.5, 24.0, 25.0, 26.0, and 30.0 mL. Sketch the titration curve.
A 0.2g sample of toothpaste containing fluoride was treated with 50 cm3 of a suitable buffer solution and diluted to 100 cm3. Using a fluoride ion-selective electrode, a 25.00 cm3 aliquot of this solution gave cell potentials of –155.3 mV before and –176.2 mV after spiking with 0.1 cm3 of a 0.5 mg/cm3 fluoride standard. Calculate the pF– corresponding to each cell potential and the percentage by weight of fluoride in the toothpaste.