Calculate the conditional formation constant (K'' NiY) of the [NiY]2- complex in 0.050 M NH3 and 0.090 M NH4Cl buffer solution. The formation constants of nickel amine complexes are respectively K1 = 102.75, K2 = 102.20, K3 = 101.69, K4 = 101.15, K5 = 100.71, K6 = 10-0.01. (KNiY = 4.2x1018, KNH3 = 1.74x10-5)

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter32: Radiochemical Methods
Section: Chapter Questions
Problem 32.17QAP
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Calculate the conditional formation constant (K'' NiY) of the [NiY]2- complex in 0.050 M NH3 and 0.090 M NH4Cl buffer solution.

The formation constants of nickel amine complexes are respectively K1 = 102.75, K2 = 102.20, K3 = 101.69, K4 = 101.15, K5 = 100.71, K6 = 10-0.01. (KNiY = 4.2x1018, KNH3 = 1.74x10-5)

pH
a4
1
7,52E-18
2.
3,71E-14
2,51E-11
4
3,61E-09
3,54E-07
6
2,25E-05
7
4,8E-04
8
5,39E-03
0,052
10
0,35
11
0,85
12
0,98
13
1,00
14
1,00
3.
00
Transcribed Image Text:pH a4 1 7,52E-18 2. 3,71E-14 2,51E-11 4 3,61E-09 3,54E-07 6 2,25E-05 7 4,8E-04 8 5,39E-03 0,052 10 0,35 11 0,85 12 0,98 13 1,00 14 1,00 3. 00
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