Calculate the initial concentration of F e^ 3+ and SCN^ - , accounting for dilution using C1V1 = C2V2 for each solution in Table 2. Show an example calculation for solution A for both the iron(III) and thiocyanate ions. Enter all calculated values into Table 3.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter24: Introduction To Spectrochemical Methods
Section: Chapter Questions
Problem 24.16QAP
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Please Answer Fast: Calculate the initial concentration of F e^ 3+ and SCN^ - , accounting for dilution using C1V1 = C2V2 for each solution in Table 2. Show an example calculation for solution A for both the iron(III) and thiocyanate ions. Enter all calculated values into Table 3.
Soln.
A
B
C
D
E
Table 3: Calculations for Determina
3+
Initial [Fe³+] M
(accounting for
dilution)
Initial [SCN] M
(accounting for
dilution)
Transcribed Image Text:Soln. A B C D E Table 3: Calculations for Determina 3+ Initial [Fe³+] M (accounting for dilution) Initial [SCN] M (accounting for dilution)
Soln.
A
B
C
D
E
mL of Fe³+
(2.00×10-³ M)
CI
V₁
3.00
3.00
3.00
3.00
3.00
Table 2: Analysis of Solutions Used to Determine Kc
mL of SCN-
Absorbance Values
at 447 nm
(4.00×10-3 M)
Vi
move
EI
1.00
2.00
3.00
4.00
5.00
Average
Absorb.
0.092 0.159 0.2020.149 0.082o. 159 0.167
0.185 0.294 0.375 0.278 0.1850.292 0.285
*
0.498 0.4200.54€ 0.420 +498 0.416 0.458
0.844 0.5380.6820.528 0.344-0.6020.539
*
0.4180.684 0.930 0.6426.48 0.718 0.649
Note: All final volumes were 10.00 ml made up with 0. 500 M HNO3.
Transcribed Image Text:Soln. A B C D E mL of Fe³+ (2.00×10-³ M) CI V₁ 3.00 3.00 3.00 3.00 3.00 Table 2: Analysis of Solutions Used to Determine Kc mL of SCN- Absorbance Values at 447 nm (4.00×10-3 M) Vi move EI 1.00 2.00 3.00 4.00 5.00 Average Absorb. 0.092 0.159 0.2020.149 0.082o. 159 0.167 0.185 0.294 0.375 0.278 0.1850.292 0.285 * 0.498 0.4200.54€ 0.420 +498 0.416 0.458 0.844 0.5380.6820.528 0.344-0.6020.539 * 0.4180.684 0.930 0.6426.48 0.718 0.649 Note: All final volumes were 10.00 ml made up with 0. 500 M HNO3.
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