Consider the reaction: NH2COONH4 (s) = 2 NH3 (g) + CO2 (g) At high temperatures such as 250.°C, the equilibrium constant for the reaction is 1.58 x 10-8. A research student ran the experiment by first placing 39.1 g of the reactant compound in a 750. mL evacuated closed container. (R = 0.08206 L.atm/K.mol; K = °C + 273; pay attention to sig figs) a) Write the equilibrium expression, Kc, for this reaction. kc=l.58 x 10 COONH kc [NH3]? [COz] b) What is the concentration of each of the products at equilibrium? NH2COONH4 (s) = 2 NH3 (g) + CO2 (g) NHz COON H4: 39.1g 78.070 gimol 50 mol NH2 COON Hy = Z NH3 CO2 Tnitial -50 gimo1 W 999. + 2 X t ズ ミGGG N •150L E : 666-X answer: ENHS] = 2(-89x104) :1.78x10-4 M C COz] = -89x 10 4 M kc CNH3]?CCO1] →1.58* 10°8-(2x) Cx) 2x2.1.58x 1 X: 1.58x108 c) What is the pressure in atm exerted by each of the products at equilibrium? on 79x 10 こ、 kp= kc x (RT) X= .89x104 R=. 08206 kp:1.58x10-8 x(.08206x523)? :1,58 x 108x (42.91738)? : 2.9|x 10-5 n (3-1) = 2 入 T 523 k -5 [NH3]=2(,0302) = . O605 altm X= .0302 COL): 10302 atm d) Use these pressures to calculate the Kp for the reaction at this temperature. d) Use these pressures to calculate the K, for the reaction at this temperature. e) What is the total pressure in the container at equilibrium. f) If the reaction was initially set up with 95.5 g of the reactant instead of the 39.1 g, and all other conditions were the same , what are the concentrations of each of the products at equilibrium?
Consider the reaction: NH2COONH4 (s) = 2 NH3 (g) + CO2 (g) At high temperatures such as 250.°C, the equilibrium constant for the reaction is 1.58 x 10-8. A research student ran the experiment by first placing 39.1 g of the reactant compound in a 750. mL evacuated closed container. (R = 0.08206 L.atm/K.mol; K = °C + 273; pay attention to sig figs) a) Write the equilibrium expression, Kc, for this reaction. kc=l.58 x 10 COONH kc [NH3]? [COz] b) What is the concentration of each of the products at equilibrium? NH2COONH4 (s) = 2 NH3 (g) + CO2 (g) NHz COON H4: 39.1g 78.070 gimol 50 mol NH2 COON Hy = Z NH3 CO2 Tnitial -50 gimo1 W 999. + 2 X t ズ ミGGG N •150L E : 666-X answer: ENHS] = 2(-89x104) :1.78x10-4 M C COz] = -89x 10 4 M kc CNH3]?CCO1] →1.58* 10°8-(2x) Cx) 2x2.1.58x 1 X: 1.58x108 c) What is the pressure in atm exerted by each of the products at equilibrium? on 79x 10 こ、 kp= kc x (RT) X= .89x104 R=. 08206 kp:1.58x10-8 x(.08206x523)? :1,58 x 108x (42.91738)? : 2.9|x 10-5 n (3-1) = 2 入 T 523 k -5 [NH3]=2(,0302) = . O605 altm X= .0302 COL): 10302 atm d) Use these pressures to calculate the Kp for the reaction at this temperature. d) Use these pressures to calculate the K, for the reaction at this temperature. e) What is the total pressure in the container at equilibrium. f) If the reaction was initially set up with 95.5 g of the reactant instead of the 39.1 g, and all other conditions were the same , what are the concentrations of each of the products at equilibrium?
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter12: Chemical Equilibrium
Section: Chapter Questions
Problem 61QRT
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