Chloride ions are added to the Ag|Ag+ half-cell of the cell Ag|Ag+||Cu2+|Cu to precipitate AgCl (s). The cell voltage is then measured to be +0.70 V at 298 K. If [Cu2+|Cu half cell, what is [Ag+] in the Ag|Ag+ half-cell?   Ecell=E֯cell-(0.0257 V/n) ln(Q) E֯cell= E֯ox + E֯red

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter17: Electrochemistry
Section: Chapter Questions
Problem 75QAP: Consider a cell in which the reaction is 2Ag(s)+Cu2+(aq)2Ag+(aq)+Cu(s) (a) Calculate E° for this...
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Chloride ions are added to the Ag|Ag+ half-cell of the cell Ag|Ag+||Cu2+|Cu to precipitate AgCl (s). The cell voltage is then measured to be +0.70 V at 298 K. If [Cu2+|Cu half cell, what is [Ag+] in the Ag|Ag+ half-cell?

 

Ecell=E֯cell-(0.0257 V/n) ln(Q)

E֯cell= E֯ox + E֯red

 

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