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- M 6 write the principal product in a, c & e and the neccesary reactives for b, d & f in the following reactions :The replacement of CH3OH to dimethyl sulfoxide, DMSO (CH3)2S=O) as a solvent in the substitution reaction below results in what?Draw all of the substitution and elimination products formed from thegiven alkyl halide with each reagent: (a) CH3OH; (b) KOH. Indicate thestereochemistry around the stereogenic centers present in the products,as well as the mechanism by which each product is formed.
- cis-4-Bromocyclohexanol and trans-4-bromocyclohexanol form the same elimination product but a different substitution product when they reactwith HO-. a. Why do they form the same elimination product?b. Explain, by showing the mechanisms, why different substitution products are obtained.c. How many stereoisomers does each of the elimination and substitution reactions form?Plastic photochromic sunglasses are based on the following reversible rearrangement of a dye inside the lenses that occurs when the lenses are exposed to sunlight. The original dye absorbs UV light but not visible light and is thus colorless, while the rearrangement product absorbs visible light and is thus darkened. (a) Show the mechanism of the rearrangement. (b) Why does the rearrangement product absorb at a longer wavelength (visible light) than the original dye (UV)?Which compounds from 5a-d will react with hydroxide in the fashion shown. Which reaction will be the fastest and slowest? Explain using knowledge of carbonyl chemistry, pka and leaving groups.
- What products would ypu obtain from reaction of 2,4-dimethyl-2-pentene with BH3, followed by H2O2, OH-? Show its complete reaction mechanism.Chemistry Q: Kindly explain the striking observation that methylation of the alcohol 1 leads to a methoxy compound in which the stereochemistry of the oxygen has changed. Explain it by providing a mechanism accounting for the transformation. (write legibly pls).There are two isomeric cyclohexa-1,4-diene products when benzoic acid undergoes the Birch reduction (see Problem 25.24). (a) Draw the mechanism that leads tothe formation of the major product. (b) Will the Birchreduction of benzoic acid occur faster or slower than theBirch reduction of benzene itself? Hint: Is –CO2H anelectron-donating or an electron-withdrawing group?
- Draw the organic product(s) of reaction of the alkyne above with H3O+ in the presence of HgSO4 (shown in two different angles)Reaction of 2° alcohol A with HCl forms three alkyl chlorides, all of whichresult from rearrangement of the 2° carbocation initially formed. Draw thestructures of these products and a mechanism that illustrates how eachis formed.