Claisen and Dieckmann condensations involve two ester groups in their reactions.CH,CH,IIC-O-C,H,CH2.C-O-C,H,CH,(i)Referring to the reaction above, suggest a suitable base for the reaction.(ii)Write the detailed mechanism for the reaction in (c)(i).

This question belong to the carbonyl compound and its derivatives. Claisen and Dieckmann…

Claisen and Dieckmann condensations involve two ester groups in their reactions. - CH, - CH, `C-O-C,H5 C-O-C,H5 CH, CH2 (i) Referring to the reaction above, suggest a suitable base for the reaction. (ii) Write the detailed mechanism for the reaction in (c)(i).

Claisen and Dieckmann condensations involve two ester groups in their reactions. - CH, - CH, `C-O-C,H5 C-O-C,H5 CH, CH2 (i) Referring to the reaction above, suggest a suitable base for the reaction. (ii) Write the detailed mechanism for the reaction in (c)(i).

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions

Section: Chapter Questions

Problem 20.54P

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Concept explainers

Aromatic Compounds

Aromatic organic compound or aromatic system is an important class of hydrocarbons under the branch of organic chemistry. Aromatic compounds are also called arenas. The definition of aromatic organic compounds can be stated as a class of organic compounds with a planar cyclic ring of atoms bonded through alternated single and double bonds. Due to these alternating bonds, a peculiar feature termed as ‘resonance’, that is, delocalization of pi electrons or the electrons is shared within the atoms of the ring which are present in the aromatic compounds. The word ‘aromatic’ includes a Greek word ‘aroma’ which means smell, indicating that they were named as such due to the sweet odor they produce. Many well-known flavors such as vanilla, cinnamon, and few scents from flowers are extracted from aromatic compounds. Benzene with chemical formula C6H6 is a very common aromatic compound that contains six atoms of carbon held in the cyclic ring of alternate double bonds. It is also to be noted that not all aromatic compounds contain benzene ring. This can be explained by Huckel’s rule.

Question

Claisen and Dieckmann condensations involve two ester groups in their reactions.
CH,
CH,
II
C-O-C,H,
CH2.
C-O-C,H,
CH,
(i)
Referring to the reaction above, suggest a suitable base for the reaction.
(ii)
Write the detailed mechanism for the reaction in (c)(i).

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