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- Your body deals with excess nitrogen by excreting it in the form of urea, NH2CONH2. The reaction producing it is the combination of arginine (C6H14N4O2) with water to give urea and ornithine (C5H12N2O2). C6H14N4O2 + H2O ? NH2CONH2 + C5H12N2O2 [Molar masses: 174.2 18.02 60.06 132.2] If you excrete 95 mg of urea, what quantity of arginine must have been used? What quantity of ornithine must have been produced?Neeeedeedddddd helpppppp1) For an open system with PCO2=10−3.5 atm what fraction of the total carbonate is in the form of CO32− at pH 10.63? 2) Using paleolimnological methods it is possible to estimate past pH values of surface waters. If the estimate of pH is 5.787 , what is the corresponding PCO2? in atm.
- Hydroxyapatite, Ca10(PO4)6(OH)2 , has a solubility constant of Ksp = 2.34×10−59, and dissociates according to Ca10(PO4)6(OH)2(s)↽−−⇀ 10Ca2+ (aq) + 6PO3−4 (aq) + 2OH− (aq) Solid hydroxyapatite is dissolved in water to form a saturated solution. What is the concentration of Ca2+ in this solution if [OH−] is fixed at 9.60×10−4 M ?One gram of sodium hydroxide (NaOH) is used to adjust the pH of an aqueous solution (200 gallons) thatcontains 10 lbs of finely ground rhodochrosite (MnCO3) ore. Does the NaOH raise or lower the solutionpH? What is the amount of NaOH added in lbs/ton? What is the molarity (mol/l) of the system? Assumingthe NaOH is completely soluble and the system is at room temperature, what is the solid-to-liquid ratio(wt%) of the system?The Ksp value for magnesium arsenate [Mg3(AsO4)2] is 2.00 X 10-20 so if a chemist added 1.19 x 10-2 M of Pb3(AsO4)2(aq) which is a common ion then what would be the concentration of the Arsenate ion AsO43-(aq) in Molarity at equilibrium? 1.97 x 10-2 2.78 x 10-2 2.38 x 10-2 1.74 x 10-2 3.24 x 10-2 2.99 x 10-2 2.57 x 10-2 2.11 x 10-2 1.55 x 10-2 1.35 x 10-2
- The Ksp value for magnesium arsenate [Mg3(AsO4)2] is 2.00 X 10-20 so if a chemist added 1.19 x 10-2 M of Pb3(AsO4)2(aq) which is a common ion then what would be the concentration of the Magnesium ion Mg2+(aq) in Molarity at equilibrium? 3.89 x 10-6 4.07 x 10-6 3.47 x 10-6 2.45 x 10-6 2.81 x 10-6 3.28 x 10-6 2.64 x 10-6 3.69 x 10-6 3.01 x 10-6 4.29 x 10-6. A student prepares a solution by dissolving 1.000 mol ofNa2SO4 in water. She accidentally leaves the containeruncovered and comes back the next week to find only awhite, solid residue. The mass of the residue is 322.2 g.Determine the chemical formula of this residue.The commercial production of nitric acid involves thefollowing chemical reactions:4 NH31g2 + 5 O21g2¡4 NO1g2 + 6 H2O1g22 NO1g2 + O21g2¡2 NO21g23 NO21g2 + H2O1l2¡2 HNO31aq2 + NO1g2 (a) Predict what kind of reaction dopamine is most likely toundergo in water: redox, acid-base, precipitation, or metathesis?Explain your reasoning. (b) Patients with Parkinson’sdisease suffer from a shortage of dopamine and may need totake it to reduce symptoms. An IV (intravenous fluid) bag isfilled with a solution that contains 400.0 mg dopamine per250.0 mL of solution. What is the concentration of dopaminein the IV bag in units of molarity? (c) Experiments withrats show that if rats are dosed with 3.0 mg/kg of cocaine(that is, 3.0 mg cocaine per kg of animal mass), the concentrationof dopamine in their brains increases by 0.75 mM after60 seconds. Calculate how many molecules of dopaminewould be produced in a rat (average brain volume 5.00 mm3)after 60 seconds of a 3.0 mg/kg dose of cocaine.
- TypeFormulaKsp Solubility Product Constants (Ksp at 25 oC) TypeFormulaKspBromidesPbBr26.3 × 10-6AgBr3.3 × 10-13CarbonatesBaCO38.1 × 10-9CaCO33.8 × 10-9CoCO38.0 × 10-13CuCO32.5 × 10-10FeCO33.5 × 10-11PbCO31.5 × 10-13MgCO34.0 × 10-5MnCO31.8 × 10-11NiCO36.6 × 10-9Ag2CO38.1 × 10-12ZnCO31.5 × 10-11ChloridesPbCl21.7 × 10-5AgCl1.8 × 10-10ChromatesBaCrO42.0 × 10-10CaCrO47.1 × 10-4PbCrO41.8 × 10-14Ag2CrO49.0 × 10-12CyanidesNi(CN)23.0 × 10-23AgCN1.2 × 10-16Zn(CN)28.0 × 10-12FluoridesBaF21.7 × 10-6CaF23.9 × 10-11PbF23.7 × 10-8MgF26.4 × 10-9HydroxidesAgOH2.0 × 10-8Al(OH)31.9 × 10-33Ca(OH)27.9 × 10-6Cr(OH)36.7 × 10-31Co(OH)22.5 × 10-16Cu(OH)21.6 × 10-19Fe(OH)27.9 × 10-15Fe(OH)36.3 × 10-38Pb(OH)22.8 × 10-16Mg(OH)21.5 × 10-11Mn(OH)24.6 × 10-14Ni(OH)22.8 × 10-16Zn(OH)24.5 × 10-17IodidesPbI28.7 × 10-9AgI1.5 × 10-16OxalatesBaC2O41.1 × 10-7CaC2O42.3 × 10-9MgC2O48.6 × 10-5PhosphatesAlPO41.3 × 10-20Ba3(PO4)21.3 × 10-29Ca3(PO4)21.0 × 10-25CrPO42.4 × 10-23Pb3(PO4)23.0 × 10-44Ag3PO41.3 × 10-20Zn3(PO4)29.1 ×…What is the concentration of free Ag+(aq) in a solution that is initially 0.01254 M in AgNO3 and 1.04842 M NH3? These two compounds react together to form [Ag(NH3)2]+. Kf([Ag(NH3)2]+) =1.600e7 1.023 7.484e-10 0.01254 6.250e-8You are on one of Saturn's many moons and discover a substance, Y2O that undergoes autoionization just like water on Earth. Y2O + Y2O ⇌ Y3O+ + OY– Through a series of experiments, you determine the equilibrium constant (Keq) for this autoionization reaction at various temperatures. The value of Keq at 28.7ºC is 7.6 x 10-14. What is the pY of the pure substance at this temperature? Report your answer to the hundreths place
