Common exceptions to the octet rule are compounds and polyatomic ions with central atoms having more than 8 electrons around them. Phosphorus pentafluoride, PF5; sulfur tetrafluoride, SF4; xenon tetrafluoride, XeF4; and tri-iodide ion, I3, are all examples of exceptions to the octet rule.  (a) Draw the Lewis structures of these substances. (b) For which elements in these substances can the atoms have more than 8 electrons around them? (c) How can the atoms of the elements you identified in Part (b) be surrounded by more than 8 electrons?

Chemistry: The Molecular Science
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ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
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Chapter6: Covalent Bonding
Section6.8: Formal Charge
Problem 6.8PSP
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Common exceptions to the octet rule are compounds and polyatomic ions with central atoms having more than 8 electrons around them. Phosphorus pentafluoride, PF5; sulfur tetrafluoride, SF4; xenon tetrafluoride, XeF4; and tri-iodide ion, I3, are all examples of exceptions to the octet rule. 
(a) Draw the Lewis structures of these substances.
(b) For which elements in these substances can the
atoms have more than 8 electrons around them?
(c) How can the atoms of the elements you
identified in Part (b) be surrounded by more
than 8 electrons?

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